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姜有为:打造营商环境 推动沈阳高质量发展

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Element 7: ???????? (N), ?? ???
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Element 9: ???? (F), ???????
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Element 11: ?????? (Na), ??? ????
Element 12: ???????? (Mg), ??? ???? ?????
Element 13: ???????? (Al), ??? ????
Element 14: ??????? (Si), ??? ???
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Element 18: ????? (Ar), ??? ????
Element 19: ???????? (K), ??? ????
Element 20: ??????? (Ca), ??? ???? ?????
Element 21: ???????? (Sc), ??? ???????
Element 22: ???????? (Ti), ??? ???????
Element 23: ???????? (V), ??? ???????
Element 24: ???? (Cr), ??? ???????
Element 25: ?????? (Mn), ??? ???????
Element 26: ???? (Fe), ??? ???????
Element 27: ?????? (Co), ??? ???????
Element 28: ???? (Ni), ??? ???????
Element 29: ???? (Cu), ??? ???????
Element 30: ??? (Zn), ??? ???????
Element 31: ?????? (Ga), ??? ????
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Element 37: ???????? (Rb), ??? ????
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Element 40: ???????? (Zr), ??? ???????
Element 41: ??????? (Nb), ??? ???????
Element 42: ????????? (Mo), ??? ???????
Element 43: ???????? (Tc), ??? ???????
Element 44: ???????? (Ru), ??? ???????
Element 45: ?????? (Rh), ??? ???????
Element 46: ??????? (Pd), ??? ???????
Element 47: ??? (Ag), ??? ???????
Element 48: ??????? (Cd), ??? ???????
Element 49: ?????? (In), ??? ????
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??? ??? ?????? (?? ????? ?????) 132±3? 百度 注册土木工程师(水利水电工程)英文译为:RegisteredengineerofCivilengineering(WaterresourcesHydropower)。

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55Fe ????? 2.73 ??? ε 0.231 55Mn
56Fe 91.72% 56Fe ?? ???? ????? ??? 30 ???????
57Fe 2.2% 57Fe ?? ???? ????? ??? 31 ???????
58Fe 0.28% 58Fe ?? ???? ????? ??? 32 ???????
59Fe ????? 44.503 ??? β? 1.565 59Co
60Fe ????? 2.6×106 ??? β? 3.978 60Co

?????? ????? ??????? ???? Fe ????? ?????? 26? ????? ??? ????? ??????? ?????? d ???? ??? ??? ????? ???????? ??????? ?? ?????? ??????? ?????? ????????? ??? ???????? ??????????. ?????? ??? ?????? ???? ?????? ?? ??????? ?????? ?? ??? ???? ??????? ?????????? ?? ????? (32.1%)? ??????? ?? ????? ??????? ?????? ??????? ?? ???? ?????? ?? ??? ???? ?? ??????? ??????? ?? ??? ???? ??????? ?????????? ?? ?????? ???????? ???? ??? ???????? ?????????? ???????????? ??? ???? ???????? ????? ?? ?????? ???????? ???? ????? ????? ?????? ?? ???? ?? ????? ??????.

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???? ?????? ?? ?????? ?????? ??????? ?? ?????? ?? ?????? ???????? ??? ??? ???? ?? ??? ????? ????? ????? ????? ????? ??????. ???????? ????? ?????? ?? ?????? ?????? ?????? ??????? ??? ????? ?????? ??????? ????? ??????? ??????? ?? ?????? ?????? ??????????? ????? ???? ?????? ?????? ?????????. ??? ????? ?? ?????? ???????? ?????? ??????? ??? ????? ????? ????? ?????????? ???? ??? ?????? ???? ????? ???? ?? ?????? ????? ?? ????? ??? ????? ??? ?????? ????? ????? ????? ?????? ??? ??? ????? ?????? ????? ??????. ?? ??????? ?????????? ?????? ????? ????? ???????? ???? ?????? ??????? ??????? ???????. ????? ?????? ?? ?????? ??????? ?? ???? ???????? ?????????? ??????? ??? ?? ??? ??????? ???????? ??????? ????????????: ?????????? ??????????. ????? ?????? ????? ?????? ?? ????????? ?????????? ?? ????? ????? ??????? ?? ?2 ??? +7? ???????? ??? ????? ???? ?? ????????? ????????? ??? ?????????? ?????? ??????? ?????????? ????? ??????? ????? ??? ???? ?? ????????? ????????.

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??? ?? ?????? ??????? ?? ????? ???????? ??????? ??????? ?????? ?? ??????? ??? ??????? ???? ??? ????? ????? ??????? ??? ????? ?? ?????? ?? ???? ??????? ?????????? ???????? ??? ??? ????? ?? ??? ?? ??? ???????? ?? ???? ????? ???? ???????? ???????? ??? ??????? ??????? ??? ???????? ????? ??????? ?? ???????.[2] ??????? ??? ????? ?? ?????? ?????? ???? ??????? ??????????? [?????? 3]? ??? ?????? ??????? ????? ???? ?????? ??? (5-18%). ?????? ???????? ??? ??? ?????? ??????? ??????? ???? ???? ?? ????? ???????????? ??????? ???? ??? ????? ?? ???????[de 2] ???? ?????? ?? ????? ??????? ???????? ??????? ????? ??? ????? ???????? ??? ???????? ?? ????? ??????? ???????? ?? ???? ????.[de 3] ??????? ?? ??? ??????? ??? ??????? ?????? ?????? ?? ?????? ???????? ????? ???? ??? ????? ??????? ????? 3500 ??? ??? ???????.[1][3] ??? ?????? ????? ??? ????? ?? ?????? ??????? ?? ??? ??? ??? ????? ??? ???? ????? ??????? ??? ???? ??????? ?????????? ?? ?????? ????????? ??????? ?????? ??????? ?? ???? ??????? ?????? ?????? ?? ??? ???????? ????? ???? ???? ??? ?? ???? ???? ??????.[4][5][6]

?????? ????? ?? ????? ???? ???????? ??? ???????? ??????? ??????? ?? ?????? ???????? ??????? ?? ????? ??? ?????? ??? ????? ?? ???? ?????? ?? ???? ????? ???? ??? ??????? ???????? ??? ????? 3100 ??? ??? ???????.[de 2] ????????? ?? ??????? ?????? ???? ?????? ??????? ????? ??????? ??????? ?????? ????? ??????? ??? ????? ?????? ??? ??????? ???? ?? ????? ?? ?????? ??? ??????? ???? ???????? ?????? ?????? ?????? ???.[de 4]

????????? ?? ??????? ???????

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???????? ?????? ???? ?? ???????? ?????? ?? ???? ?????? ?? ???? ???? ????? ??? ???? ??????? ?????? ?? ??? ??? ???? ??????? [?????? 4]? ??? ????? ?? ???? ??????? ???????? ????????.

??? ????? ?????? ??? ????? ???????? ??????? ??? ????? ????? ????? ???? ????? ??? ??? ??? ?????? ???? ??????? ?? ????? ??????? ????????. ?? ??? ??????? ??????? ?????? ???? ??????? ??? ???? ????? ?????? ?? ?????? ?????? ???? ??? ??? ????? ???????? ????? ??????? ???????? ??????? ??????. ???? ????? ?????? ?????? ??????? ???? ???????? ???? ????? ?????? ???????? ?????? ??????? ???????? ????? ??? ??????? ??????? ???????? ?? ??????? ???????? [?????? 5]? ??? ????? ???? ???? ????? ????? ??. ???? ????? ??????? ?????????? ?? ???? ?????? ????? ???????? ????? ????? ??? ????? ??????? ?? ?????? ???????? ?? ???? ????? ??? ??? 3000 ??? 2700 ??? ??? ???????.[1] ?? ????? ?? ?????? -??????? ?????? ?? ??????- ??? ????? ?? ???? ?????? ?? ????? ???? ?? ??????? ?? ???? ??? ???????? ?? ?????? ?????? ???? ?? ??????? ????????.[de 2][7][8]

???? ???? ??????? ????? ??? ??????? ?????? ???????? ?? ????? ???????.

????? ????????? ??? ?????? ?????? ?? ???? ???????? ??????? ?? ????? ????? ??? ??? ??? ?????? ??? ??????? ????? ???? ????? ?????? ????? [?????? 6] (????? 1800 ??? ??? ???????)?[de 2] ????? ?????????? ??? ???? ???????? ???? ?????? ?? ?????? ?? ??? 1500 ??? 1200 ??? ??? ???????? ???? ?? ?????? ?????? ???? ?????? ???? ?????? ???? ???? ?? ?????? ????? ??????? ?? ?????.[9][10] ?? ??????? ??? ???????? ?????? ?? ???????[11] ??? ?????? ????? ?????? ?? ????????? ?? ????? ?????? ??? ??? ????????[2] ????? ??? ??????? ?????? ?? ???? ????? ????? ?????? ??? ??? ???? ?????????? ???????? ????? ??? 1180 ??? ??????? ?? ?????? ????????? ???? ????? ????? ????? ???????.[1][de 1] ?????? ????? ????? ??????? ???????? ??????? ???????? ????????? ???? ???? ????? ?? ????? ????????? ??????? ??????? ?????? ?? ????? ??????? ?? ???? ?????? ??????? ?????????? ????? ?????? ???? ?????? ?? ????? ??????? ??????? ??????? ?????? ??? ????? ????? ??????? ???????? ??????? ??????. ????? ?????? ????? ?????? ?????? ??? ????? ???????? ????? ?? ??? ??????? ?????? ?????? ????? ??????? ????? ??? 900 ??? ???????. ??? ??? ??? ??????? ???? ???? ?????? ??? ???? ??????? ???? ??? ????? ???????? ??? ??????? ????? ???? ????? ??????? ??? ?? ??? 663 ??? ???????? ?????? ??? 500 ??? ??????? ????? ?????? ???????? ????????? ?????? ??????.[12]

????? ?????? ?? ???????? ???????? ????? ??? ?????? ???? ?? ????? ?????? ?????? [?????? 7]? ???? ????????? ?? ??????? ????? ???? ?????? ?????? ?? ????? ??????? ?????? ????? 1000 ??? ??? ???????.[1] ????? ???? ??????? ???? ???? ????? ????? ????? ??????? ?? ???? ??????? ????? ??? ??? ?????? ?? ?????? ????????? ????? ????? ?????? ??? ???????? ???? ?? ????????[1] ????? ??????? ???????[13] ???? ?? ????? ???? ??? ??? ????? [?????? 8] ?? ??????? ??? ???? ?????? [?????? 9] ?????? ???? ???? ???????.[de 1]

??? ???? ??? ?????? ??????? ??????? ?? ??????? ????????? ?????? ??????? ?? ???? ??? ??????? ??? ????? ?????? ??????? ?? ???? ??? ?????? ?? ?????? ??????? ??? 1800 ??? 1200 ??? ??? ??????? ?? ??????[14] ???? ???? ?????? ??? ?????? ?? ?????? ????????? ??? ??????????? [?????? 10].[15] ??? ???? ??? ??? ????? ?????? ??????? ??? ??????? ????????? [?????? 11] ????? 300 ??? ??? ???????.[de 2] ??? ???? ????? ?????????? ????? ??????? ?? ????? ????? ????? ?????? ???? ?????? ????? ?????? ??????? ?? ????? ???? ????? ?????? ????? ???????.[16] ?????? ??? ?????? ?? ????? ??? ????? ????? ????? ?????? ????????? ?? ????? ??????? ?????? ?? ????? ?? ?????? ?? ??? 700 ??? 500 ??? ??? ????????[17] ????? ????? ??????? ??? ?????? ?? ???? ????? ??? ???? ??????.[18] ???? ???????? ?? ????? ???? ????? ???? ???? ?? ????? ?????? ??? ???????.[19] ?????? ??? ???? ?????? ???????? ?? ?????? ????? ?? ????? ?? ?????? ???????? ???????? ???????? ??????? ?? ???? ????? ??????? ??? ?????? ????????.[20] ??????? ????? ??????? [?????? 12] ?? ?????? ????? ???? ??????? ????????? (403–221 ??? ??? ???????).[de 5] ??? ??????? ??????? ??????? ?????? ??????? ????????? ???? ????????? ???????? ???? ????? ?????????????.[21][22]

???? ????? ???? ??? ??????? ???????.

???? ???? ?????? ???????? ?????? ?? ??????? ????????? ??? ????? 2000 ??? ??? ??????? ??? ??? ?????? ?? ???? ????? ?????? ?????? ??? ????? ????.[de 2] ????? ??????? ?????? ?? ??????? ??????? ?? ????? ????? ?????? ??? ??? ???????? ????? ??? ??? ??????.[de 6] ???? ??? ????????????? ?? ??????? ???????????? ???????????? ?????? ?? ????? ?? ????? ??????? ????????? ?????? ?? ???? ????????? ??????? ????????? ??????? ??? ???? ??? ????? ????? ?????? ??? ???????.[de 7] ??????? ????? ??????? ?? ??? ?????? ??? ??????? ??????????? ???? ????? ??????? (?? 800-450 ??? ??? ???????) ?????? ????? (????? ?? 450 ??? ??? ???????).[de 1] ????? ?????? ????? ?????? ?? ??? ????? ?????? ?? ????? ?????? ?????? ?????? ???????? ?????? ??? ??????? ?????? ?????? ?? ???? ???? ???????.[1]

?????? ??????

[???]
?????? ????? ???? ??? ????? ?????? ??? ???? ??????? ?????? ?? ???? ????? ?? ????? ????? ?????? ???????.

????? ???? ?????? ?????? ?????? ????? ????? ?????? ???????? ?? ?????? ????? ??????? ???? ???? ?????? ?????? ??????? ??? ?????? ??????? [?????? 13]? ???? ???? ????? ??????? ???????? ?? ??? ?????????.[23] ?????? ????? ?????? ???? ????? ????????? ???????? ???? ????? ?????? ???????? ???? ??? ????? ?????? ?????? ???????. ?????? ????? ?????? ??? ?????? ??? ??????? ?? ???????? ????????? ????? ?? ??????? ????? ??????? ????? ??? ???? ?????? ?????.[24] ??? ???? ?????? ???? ??? ??????? ?? ???? ????? ?????? ?? ???? ?????? ???????? ?????????.[25] ???? ????? ?? ????? ?????? (? 260??? 873?) ??????? ?? ?????? ??????? ?????? ????? ??????? ??? ????? ?????? ?? ?????? ???????? ??????? ???? ?? ?????? ????? ??????? ???? ?? ??????? ??? ???? ????? ?????? ???? ??? ?? ??? ???? ????? ??? ????? ?? ??????? ?????? ??? (0.5 ? 1.5%)? ??? ????? ????? ????????? ??? ?????? ??????? ???? ?? ?????? ??? ????? ???? ?????? ?? ???? ?????? ?? ????? ????? ??? ????? ??????? ???? ?????? ??? ??? ???? ?? ????? ?? ????? ??? ????? ????? ????? ???????? ??? ???? ????? ??????? ?? ?????? ?????? ??? ??????? ???????? ????????? ?? ????? ??????? ?? ?????? ?? ??? 900 ??? ??? 1750.[26] ??????? ??? ??????? ???????? ?????? ??????? ???? ??????? ???????? ????? ????? ??? ????????? ?? ???? ?????? ???? ?????? ?? ?????.[27][28]

??????? ????? ??????? ???????? ??? ????? ?????? ?????? ?????? ???? ?????? ????? ??????? ??? ?????? ??? ????? ?????? ??? ??? ???????? ??????? ?? ???? ????? ??????? ?????? ?????? ?????? ??????? ???????? ?? ??? ?????? ??????.[29] ???????? ????? ?????? ?????? ????? ?????? ????? ?????? ?????? ???????? ????????.[de 1] ???? ?????? ??????? ??????? ?????? ??????? ??????? ???? ??? ?????? ?? ???? ??????? ?? ???? ???? ??? ?????? ????? ???? ????? ??? ????? ?? ?????? ??? ?????? ??????? ?? ??? ???? 1150 ?1300 ????????[de 8] ??? ????? ?????? ??? ???? ?????? ??? ????? ????? ?????? ?? ?????? ?? ?????? ????? ??? ????? ????????? ???????? ?? ??????? ??????? ???????.[de 9]

???? ????? ?????? ?????? ?? ??????? ??????? ???????? ?????? ?????? ??? ??? ???? ??????? ???????. ?????? ??? ??????? ??????? ?? ?????? ?????? ????? ????? ????? (???? ?????)? ????? ??????? ?? ????? ????? ???????? ???? ?????? ?????? ?????? ????? ???? ?????? ?????? ??????. ??? ??? ?????? ????? ??????? ??????? ?? ?????? ???????? ???? ????? ?? ???? ???? ??? ?????? ???? ???? ??? ???????? ?? ?????? ??????.[23]

?????? ???????

[???]
????? ????? ?? ????? ????? ?????? ??? ????? ????? ??????? ??????.

???? ??????? ????? ????? [?????? 14] ?????? ?? ??????? ????? ??????? ??????? ??????? ??????? ???? ????? ?????? ???? ????? ???? ????? ?? ????? ???????? ??? ??? 1709 ????? ????? ?? ????? ???? ???? ?? ??? ????? ?? ????? ???????? ??????????.[30] ???? ????? ????? ?????? ?????? ??????? ???? ?? ?????? ?????? ????????? ??? ???? -?? ????? ?????? ????????- ?????? ????? ?????? ?? ???? ????? ????? ??????? ???????? ??? ?????? ?? ???? ???? ???? ??????? ?? ??? 1778? ??? ?? ???? ?????? ??? ????. ???????? ??? ???? ?????? ?????? ?????? ????? ?? ???? ???? ????? ????????? ????? ???? ??????? ?? ???? ?????? ??????? ????????. ????????? ???? ?? ???? ??????? ?????? ???????? ?????????? ???????? ??? ???????? ??????? ???????.[23]

????? ???? ?????? ???????? ?? ???????? ??? ???? ???? [?????? 15] ?????? ?????? ????? ?????? ??????? ?? ???? ??? ??? ???? ????? ???????? ?????? ???????? ??? ??? 1783 ???? ???? ????? ?????? ?????? ????????? [?????? 16] ?? ??? ????? ??? ??????? ????? ?????? ??????.[31] ?????? ??????? ??????? ???????? ?????? ?? ??????? ????? ???? ???? ?? ??? ????? ?? ??????? ??? ??? 1796.[de 10] ?? ???????? ????? ?????? ??? ????? ???? ??????? [?????? 17] ?????? ?????? ?????? ???????? ????? ?????? ????? ??????? ???????? [?????? 18]? ?? ??? ?? ??????? ????? ????? ??????? ???? ????????? ?????? ???? ????? ?????? ??????? ???????? ?????.[32]

?????? ????????

[???]

???? ?????? ?? ??????? ?????? ?? ??? ???? ??????? ?????????? ?? ????? (32.1%)?[33] ?? ???? ??? ??????? ???? ???? ?? ??????? ??????? ????? ????? ??????? 28.8%.[de 11] ??? ???? ?? ??????? ??????? ?? ??? ?????? ?? ???? ????? ????? 4.70%?[de 12] ??? ??????? ??????? ????? ?? ??? ?????? ?? ?????? ??????? ????? 5.63%?[34] ???? ?? ???? ?????? ????????? ????? ???? ?????? ??????? 0.002 ????????/?????? ???.[35]

?????? ???????
???? ?????? ?????? ?? ??? ????? ?????? ????? ???? ??????? ????? ?????? ??????? ??? ????? ?????? ????? ?????????.[?????? 19].

???? ?????? ??????? ??????? ????? ????? ??????? ?????????? ??????? ?? ?????? ???? ??????? ?????? ??????? ?? ????? ??????? ??? ????????? ???????? ???? ???????? ???? ?????? ???? ?? ??????? ???????.[36] ?????? ?????? ?? ????? ????? ?????? ??????? ?? ????? ?????? ????????? ?? ?????? ????????.[de 13] ????? ????? ??? ??????? ??????? ?????? -??? ????? ??????? ??????? ???????? ??? ?????- ?????? ????? ??? ????? ??????? ?????? ?????? ?? ??????? ????? ????? ?? ????????? ?? ?????-M. ???? ???? ?????? ?? ??????? ??????? ?????? ????? ?????? ??????? ??? ???? ?????? ????? ????? ????? ?????? ???????? ??????? [?????? 20] ??????? ????????? ?????? ?? ????? Ia [?????? 21] ????? ????? ??? ????? ???? ?????? ?? ?????.[37][38] ????? ????? ?????? ??????? ??? ??? ???? ?????? ??? ????? ?????? ????? ??????? ??????.[39]

???? ?????? ?? ?????
?????????

???? ?????? ???? ??????? ?????????? ????? ?? ?????? ??????? ????? ???????? ??? ?????? ?? ???? ?????? ???? ?? ????? ??????? ?????? ??????? ???.[40][41] ????? ?????? ??????? ?? ???? ????? ?? ????? ?????? ?????????? ??????.[de 14]

???? ??????? ???????? ????? ?????? ?????? ??????? ??????? ??? ??? ?????? ????? ???????? ?????? ?? ??????? ??? ??????? ??????? ???? ??? ???? ??? ????? ?????? ???????? ?????? ?? ?????? ????????? ???? ?????? ??? ??? ??????? ????? ?????? ???? ????????? ?? ?????? ????????? ?? ??????? ???????. ?????? ????? 5% ?? ??????? ???????? ?? ???????? ???????? ???????? ?? ?????? ???????? ???? ???????? [?????? 22] (35–80% ????) ?????????? [?????? 23] (90–95% ????).[42]

???? ????? ?? ??? ??????.

????? ???? ??????? [?????? 24] ???? ??????? ???????? ???? ???? ?? ???? ???? ??? ?????? ????? ???????? ??? ???? ?? ?????? ???? ????? ?????? ????? ?? ???? ??????? ????????? ?? ??????? ???????? ????? ?????? ?? ?????? ???????? ??????? ????????? ?? ???? ??? ??????? ?? ???????? ???????? ?????? ?? ???? ???????? ??? ??? ??????? ?? ??????? ???????? ???? ??????? ?? ???? ?????? ?????? ?? ??????. ?????? ?????? ???????? ????? ???? ??????? ???????? [?????? 25] ??? ???? ??????? ?? ???? ??? ??? ????? ??????? ????? ???? ??? ????? ????? [?????? 26] ???? ????????? ????? ???? ???? ???? ?????.[43] ???? ??? ??????? ????????? ?????????? ??? ??????? ??????? ??????? ???? ?????? ?????? ????? ??? ???????.

??????? ???????? ?? ??????
???? ???? ?????????? ?? ????? ????????? [?????? 27] ?? ????? ?????? ???????.

????? ????? ???? ?? ?????? ???????? [?????? 28] (MgO) ????????? [?????? 29] ?? ???? ???? ????????????? [?????? 30]? ????? ????? ???? ????????????? [?????? 31]?[44] ??? ????? ?? ??????? ?????? ?????????? ?????? ????? 20% ?? ??? ???? ????? ??????? ??????? ??? ???? ???? ??????? ????? ?? ??? ?????? ???????? ?? ????? ??? ????????? ????????? [?????? 32] (??????? ?????? ??????????). ???? ?? ???? ??????? ?????????? ?????? ?????? ??????? ?????? ?? ????? ????? ????? ??????????? [?????? 33] (??? ???? ?? ???? ????-???????) ??? ???? ?? ????????????? ?????????? ?????????? ????? ???? ??????? ??????? ??? ??????? ????????? ??????? ???? ??????? ??????? ?????? ??????.[45][46]

?????? ???????

??? ????? ?? ???? ?????? ?? ???? ?????? ???? ??? ????? ?? ????? ?????? ??????? ???? ??? ????? 5% ?? ?????? ??????? ???? ??? ?? ??? ???? ?? ??????? ???????? ??? ???????? ?????????? ??????????? ?? ????? ??????? ?? ??? ??????.[47] ????? ???? ?????? ?? ?????? ??????? ?? ???? ?? ??????? ?????? ??? ???? ?????? ????? ????? ????? ?????? ????????. ???? ????? ???????? ?????? ??? ????? ?????? ?? ????? ?????? ?? ??????? ??????? ???? ???????? ??? ??????? ????? ??? ?? ????????? [?????? 34] (Fe2O3) ?????????? [?????? 35] (Fe3O4) ????????? [?????? 36] (FeCO3)? ???????? ????? ??? ????????? [?????? 37] (Fe2O3·n H2O) ???????? [?????? 38] (FeO·OH)? ??? ????? ???? ????? ??????.[de 15] ????????? ???????? ?????? ????? ????? ?? ????? ????????? ?????????? ?????????.[de 16]

??????? ??????? ?????? ?? ????? ???????? ?????????

???? ?????? ?? ?????? ??????? ??? ????? ????????? ?????? ??? ????????? [?????? 39] ???????????? [?????? 40].[48][49] ???? ????? ??????? ?????? ?? ?????? ?? ???? ??????? [?????? 41]? ???? ?? ????? ??????? ?????? ???. ???? ?????? ????? ?????? ??????? ??? ?? ???????? ?? ????????? ??????????? ??? ??? ????? ???????? ??? ????????? ??????????? ??? ??? ?????????? ?? ???? ???? ??????? ??? ????? ????? ???? ?? ???????? ???????? ??????? ?????? ???? ?? ????? pH ?????? ??? ??? ????? ?????? ???????.[50]

???? ???? ??????? ???????? ????? ?? ?????? ??? ???? ??????? ???????? ??? ??? ?? ????? ?????? ??????? ??? ????? ????? ?? ?????? ?????? ????????? ?? ????? ????? ??????? ??????? ?? ???????? ?????? ?????? ????????. ???? ????? ?????? ???????? ?? ??? ????????? ??? ???? ??????? ??? ??? 3700-1800 ????? ??? ????[51][52] ????? ?????? ?? ????? ?????? ?? ???????? ?????? ?? ?????? ??????? ?????? ?? ????????? ???????.[de 17] ???? ?????? ??????? ????? ????? ????? ??? ????? ???? ????? ?? ????? ?? ????? ????????? ?????? ???????? ??? ????????? [?????? 42] ????? ?????? ???? ???? ?? ????? ??????? ??? ?????.[de 16] ???? ??? ??????? ????? ?? ??? ????? ????? ?? ?????? ??????? ????? ????? ????? ?? ????? ?? ???? ????? ?????? ???????? [?????? 43] ???????? ?? ??? ?????? ???????.

????????? ????????? ???????

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??????? ??????? ?? ?????? ?? ??? 2009 ??????? ??????? ??????? [53]
????? ??? ?????? ???? ??? ???? ?????? ?????
 ????? 1,114.9 549.4 573.6
 ???????? 393.9 4.4 5.2
 ???????? 305.0 25.1 0.011 26.5
 ??????? 66.9 87.5
 ????? 257.4 38.2 23.4 63.5
 ????? 92.1 43.9 4.7 60.0
 ???????? 65.8 25.7 29.9
 ????? ???????? 0.1 27.3 48.6
 ??????? 0.4 20.1 0.38 32.7
?????? 1,594.9 914.0 64.5 1,232.4

???? ????? ?????? ??????? ?? ?????? ?? ????? ?????? ?????? ??? ?????? ??? ????? ????? ?????? ???????? ???? ?? 60% ?? ??????? ??????? ?? ??? ??????. ?? ????? ??????? ????? ?? ????? ?????? ????? ???? ?? ??????? ?????? ?????? ????????? ????????? ?????? ????????.[54] ????? ????? ??????? ??? ?????? ????????? ?????? ??????? ?????? ?? ?????? ??????? ??????? ???????? [?????? 44] ???? ????????? ??????? ?? ?????? ?? ??????? ?? 2.2 ??? ???? ????? ??? ????? ?? ????? ????????? ???? ??? ???? ??? 7-14 ??? ???? ????.[55]

???????? ??? ?????? ????? ??????? ??? ?????? ??????? ??????? ??? ?? ????? ?? ???? ?? ????? [?????? 45] ?? ???????? ????????? ??? ?????? ????? ?????? ?? ???? ?????? ????? ?? ????? ?? ???? ?????? [?????? 46] ?? ??????. ??????? ?????? ??????????? ????? ?? ??????? ?????? ?????? ???? ????? ?? ????? ?????? ?? ???? ?? ???????? ???????? ????????? ???????. ??? ??????? ??? ????? ?????? ???? ??????? ??? ?????? ????? ?? ??????? ??????? ???????? ?????? ??????? ?? ????? ??? ???????? ????? ??? ???????. ????? ????? ??? ?????? ?????? ?????? ?? ????????? ??? ???? ??? ?????? ????? ????? ??????? ?????? ????? ????? ?????? ????? ?????? ?????? ????? ?? ?????. [de 18] ?????? ??????? ????????? ?? ????? ????? ??????? ?? ??????? ??????? ??????? [?????? 47] ???????? [?????? 48]? ?????? ?????? ??????? ??? ??? ??????????? ?? ?????? ????? ??????? ?? ???? ??? ?????????? ???? ?? 2 ???????? ???? ?????????? ?????? ?????? ???? ?? ?????? ??? ????? ?????.[de 19] ?????? ?? ????? ??????? ???? ????? ??? ?????? ????? ????? ?????? ??? ???? ???? ?? ?????? ??? ???? ???????? ?????? ??????? ??? 8 ??? 18 ???????.[de 20] ?????? ????? ??????? ?? ????? ?????? ??? ????? ???????? ????? ??? ?????.[de 19]

?????? ????? ??????? ??? ??? ?????? (??????? ??????? ???????)
(??? ?????? ???? ??????? ?????????? ????????? [?????? 49])[56]

?????? ??????? ??????? ?? ?????? ????? (??????? ??????? ???????)
(??? ?????? ????? ??????? ???????? [?????? 50])[57]

???????

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????? ?????? ??? ????? ?? ????? ??????

?? ????? ?????? ?????? ????? ?????? ?? ??????? (?????) ??????? ?????? ?? ???????? ?? ??????? ?????? ??????? ??? ?????? ???????? ??? ????? ?? ??? ????? ?? ?????? ?????? ??????? ?? ??????? ?????? ???????? ?? ?????? ??? ????? ?????????. ???? ??? ??????? ?????? ?? ?????? ?????? ?????? ????????? ??? ????? ????? ?????? [?????? 51]. ?? ??????? ??????? ?????? ????? ??????? ?? ?????? ??????? ????? ??????? ???? ??? ??????? ???????? ?? ????????????? (?? ???? ?????) ?? ????????? (?? ???????).[58] ???? ????? ????? ???? ?? ??? ??????? ?? ??? ?????? ??? ????? ????? ??????.[de 21]

???????? ?????? ??????

[???]

????? ?????? [?????? 52] ?? ???? ?? ??????? ???????? ???? ???????? ?????? ??????? ??????. ?????? ????? ?????? ????????? ?? ????????? (Fe2O3) ?? ????????? (Fe3O4) ?? ??? ?????? ?? ?????? ?????? ??? ????? ?????? ?? ??????.[de 21] ???? ??? ?? ?????? ????? ??????? ?? ??? ????? ???????? ?? ???? ??????? ???? ?? ???? ????? ???? ???? ???? ??????? ??? ???? ?????? ?????? ?? ??????? ??? ???????.[ar 1]

?????? ?????? ????? ?????? ??? ??????? ????? ?? ??? ????? ????? ?? ???? ?? ????? ????? ??????? ??????????? ???? ????? ??? ??????? ??? ????? ????? ?????? ??? 1600 ??? 2200 °?. ??????? ??? ????? ??????? ?? ???? ??????? ???? ???? ????? ??????? [?????? 53]? ??? ???? ?? ??? ??????? ?? ?????? ???????? ?????? ???? ????? ??? ???? ????? ??????? 900 °? ??? ??????? ???? ???????? ????? ????? ??????? ??????? ??? ????? ????? ???????:[58]

????? ????? ????? ??????.

?? ???? ?? ????? ??????? ??? 500-900 °? ???? ?? ???? ???? ????????? ??? ????????? ??? ????? ?????? ??? ?????? ?????? ???????? ?????? ????? ???????? ??? ???? ??? ???? ????? ??? ?????? ??? ???? ?????? ???????:[de 21]

???? ?? ???? ?? ????? ??????? ??? ??? 900-1600 °? ????? ?? ???? ???? ????????? ????????? ?? ????? ??? ????? ?????? ?????? ??????? ??? ??????:[de 21]

??? ?????? ??? ????? ?? ????? ??? ?????? ??????? ??? ????? ??? ?? ??????? ??????? ?? ????? ?????? ??????? ??? ?????? ???????:[58]

???? ?????? ?????? ?????? ??????? ????? ???? ?????? ???????.

???? ????? ?? ????? ?????? (??????? ?????????) ?? ????????? (??????? ?????????? ??????????) ??? ?????? ??? ???? ????? ??? ??????? ???????? ?????? ?? ??????? ?? ???????)? ?????? ?? ????? ??????? ??????????? ?? ??????? ????? ?????? ?? ?????? ?? ?????? ????? ?????. ????? ?????? ???? ????? ????? ??? ??????? ??????? ????????? ??? ????? ?????????? ????? ?????? ????? ?? ???????? ??????? ?????? ?? ???? ???? ????????? [?????? 54]? ????? ?????? ????? ????? ?? ??????? ?????????? ???????? ??? ??????? ????.[de 22] ???? ????? ??????? ??????? ?? ????? ??????? ???? ???? ??? ?? ?????? ?????? ?? ???? ??????? ??????? ??????? ???? ?????? ???????? ?????? ??? ????????? ?? ??? ????? ????? ??????? ???? ?? ????? ????? ??????? ??? ???? ???? ????? ??? ?????? ???? ????? ?? ????? ???? ???.[58] ????? ???? ????? ??????? ???? ????? ??? ???????????? ??? ??? ???????? ????? ??? ?????. ???? ?? ???????? ??????? ?????????? ?? ????? ???????? ??? ???? ??? ????????? ???????? ??? ???????? ?? ???? ??????? ?? ??? ????? ???? ?????? ??????? ????????.

???? ?????? ????? ?????? ?? ??? ??????? ???? ??????? ????????? ??? ???? ?????? ??? 95% ????? ?? ???? ?????? ?????? ?????? ?? ??????? ?????? ??? 4–5% ?????? ???????? ??? ???? ????? ?? ????? ?????? ??? ??????? (0.01-0.05%) ????????? (0.5-6%) ?????????? (0.5-3%) ????????? (??? 2%).[de 21]

????? ???????

[???]

?????? ?? ???????? ?????? ????? (?????? ???????) ?????? ?? ????? ?????? ?? ????? ??????? ?? ????? ??????. ??? ????? ??????? ?? ?????? ??????? ???????? ??? ????? ?????? ?????? ??? 2–4% ???????? ??? ?? ????? ??????? ?????? (?? ??????? ??????) [?????? 55]? ??? ???? ?? ???????? ??? ?????? ????? ??????[de 23] ??????? ??? ??????? ?? ??????? [?????? 56] ??? ??????? ??????? ???????.[58]

????? ?????? ????? ??????? ??? ???? ??? ?????? ?????? ??? ??????? ????????? ???? ?????? ??? ????? ????? ??????? ?? ?????? ??? ???? ??????? ?????? 2%? ???????? ???????? ??? ????? ??????? (????? ???? ????? ????????? ?? ??? ????? ??????? ??? ??????? ??? ???????). ?? ??? ??? ????? ????? ??????? ??? 0.5% ????? ??? ?????? ??? ?? ???? ???? ??????? ????????.[de 24] ???? ?? ???????? ??????? ?????? ?? ??????? ?? ????? ????????? ???????? ???????? ???????? ??? ????? ??? ???? ????? ?? ????????? ????????? ??? ??????? ??? ?????? [?????? 57] ?? ?????????? ???????? ??? ?????? [?????? 58] ?? ??????? [?????? 59] ?? ??????? ????? ???????????? [?????? 60] ??????. ???? ?????? ??????? ??? ??????? ?????? ?????? ??? ??????? ??? ??????? ????????. ????? ??????? (?? ???????) [?????? 61]? ??? ????? ????? ??????? ??? ????? ????? ??? 700–800 °? ?? ???????? ?????? ????????? ?? ??? ??????? ???? ????? ????? ?????? ???????.[59]

?????? ?????? ???????

[???]

???? ????? ????? ???????? ??????? ?????? ?????? ?? ??? ?????? ??? ??????? ????? ???? ????? ???? ??????? ????????? [?????? 62]. ???? ??? ??? ??????? ??????? ?????????? ?????? ?????? ??????? ??????? ????? ??????? ??? ????? ????? ?????? ?????? ?????:

?? ????? ??? ?????? ???????? ??????? ?? ??????? ????? ???? ?????? ???? ????? ??? ?????? ??? ???? ??????? ?? ?????? ?????.

???? ??? ??????? ???? ???????? ?? ????? ???????? ????? ?? ????? ??????.

?????? ????

[???]
????? ????

???? ?????? ??? ?????? ??? ????? ??????? ???? ????? ????? ?????? ?? ????? ?? ??? ??????????? ??? ?? ????? ???????? ????????? ??????:

?? ???? ????? ??? ??????? ?? ??? ??????? ?????? ?? ?????? ?????????? ?? ?? ???? ??? ??????? ?????????? ???? ?????? ?????????? ??????? ?????? ??? ??????? ????? ?????. ???? ?????? ??? ??????? ??? ???? ???? ?????? ?? ??? ???? ???? ????? ????????.

???? ???? ??????? ??????? ????? ??????? ?????? ??? ?????? ????????? ??? ????? ?????? ??????? ?? ????? ??????? ?? ????? ???? ?? ????? ???????? ???????? [?????? 63] ?? ??? ????? ????? [?????? 64]. ??? ???? ????? ?????? ????? ????? ?? ????? ?????? ??? ????? ?????? ??? ??????? ?????????? ???????? [?????? 65] ?? ????? ????? ?????????.[58] ???????? ??? ?????? ????? ?? ??????? ??????? [?????? 66] ??? ????? ?????? [?????? 67] ??? ???? ??????? ????????? ?? ???? ?????.[60]

???? ?????? ??? ?????? ????? ??????? ???????? ????? ?? ?????? ??????? ?? ??????????? ?????? ???????? ??????????? ?? ?????? ????? ??????? ?????? ?? ?????? ??? ???? ????? ??????? 250 °? ??????? ??? ????? ???? ????.[50] ???? ?????? ??? ?????? ??? ????? ?????? ????? ?? ????? ????? ??????? ?????? ?????? ?????? ???????.[61]

???????

[???]

?????? ???? ????? ???????: ????-54 54Fe (?????? ?????? 5.845%)? ?????-56 56Fe (????? ?????? 91.754%)? ?????-57 57Fe (?????? ?????? 2.119%)? ?????-58 58Fe (?????? ?????? 0.282%). ???????? ??? ???? ???? ?????? ?????? ?????? ?????? ?? ???? ???? ????????? ?????? ??????? ??? ????? ??? ??? ??? 150 ????????? ?8.275 ????.[62] ???? ?????? ????-54 ?? ??????? ????????? ??????? ???? ????? ?? ???? ??? ???? ?? ??????? ?????? ??? ???? ??????? ????? ???????? ???? ???? ??? ????? ??? 3.1×1022 ???? ??? ?????? ??? ???? ?????? 54Cr.[63] ???? ????? ????? ??? ??????? ?????? ??? ?????? ????-60 60Fe? ????? ???? ??? ????? ?? ????? 2.6×106 ???.[64] ????? ???? ?????? ?? ?????? ??? ???? ????? ?? ?????? ???? ???? ???????? ???????? ?????? ?? ????? ??? ???? ???? ?????? 60Ni.[63]

????? ??????? ???????? ???????? ???????? ???????? ?????? ??? ??????? ?????? ??????-60 60Fe ?? ???? ????? ??????? ???????? ?????? ??????? ???????.[65] ???? ??????? ?? ???? ??????? ?????? ??? ?? ??????? ?????? ??????? ?????? ??????? ?????? ?? ??? ??????? ????????? ??????.[66] ???????? ?????? ??? ????????? ????-60 60Fe ????? ???????? ????-60 sup>60Ni ?? ????? ????? ?????? ???????? ???????. ???? ???????? ????? ??? ?????? ????????? ?? ??????? ????????? ????-60 60Fe ?????????-26 26Al ???? ?? ????? ?? ????? ??? ?????? ????????? ??? ??????? ??? ????? 4.6 ????? ???.[67] ?? ????? ???? ????? ???????? ????? ?????? ???? ????? ?????? ?????? ??? ?????? ????-56 56Fe? ????? ????? ???? ????? ??????? ?????? ??????.[68] ?????? ?????? ????-56 56Ni ??????? ?? ????? ?????? ???????? ????? ??? ????? ????? ????? ???? ?? ????? ?????? ????????? ??? ????????? ?????? ?? ????? 2 [?????? 68]. ?????? ????? ????? ???? ???? ????? ??? ???? ??????-60 ?? ?????? ??? ???? ????? 60Zn ????? ?????? ?????? ???? ??? ??????? ????? ???? ??? ??? ??????? ????? ?? ??? ??? ???? ??? ????? ???? ????? ?? ???? ??? ????? ??????? ?????? ??? ??????? ?????? ?????????? ??????? ?????? ??? ???? ???????? ?????? 56Co? ???? ??? ???? ?????? ???????? 56Fe. ???? ???? ?????? ?? ?????? ?????? ?????? ???? ???? ?????? ??????? ????????? ??? ????? ??????? ???????? ???????? ??? ?????.[69] ??? ????? ?? ???? ?????? ?? ???????? ??? ???? ???? ?? ?????? ?? ??? ????? ???? ?????? 62Ni ???? ??????? ???? ??? ?????? ???? ??? ?????? ???????? ????? ????? ?????? ??? ???????[70] ??? ?????? ????? ??????? ?????? ?? ?????? ?????? ?????? ????????? ??????[69] ???? ???? ?????? ????? ??? ???? ??????? ?????????? ????? ?? ?????.[71][72]

?????? ??????????

[???]
????? ???? ???? ???????? ??????? ??? ??? ?????????? ?? ??? ????? ??????? ????????? ?????? ???? ???? ??????-56 ?????? ?? ??????? ???????.

???? ?????? ?? ?????? ???????? ?? ????? ????? ??????? ??? ???? ???? ?? ??? ????? ????? ??? ?? ?????? ??????? ??? ???? ?????? ????? ????? ??????. ???? ????? ?????? 7.873  ?/??3? ?????? ??? 1538 °?? ????? ??? 3070  °?.[de 21] ???? ????? ?????? ?????? ??????? ???????? ??? ????? ????????? [?????? 69]? ??? ??? ???? ?? ??? ???? ????? ???????? ?????????? ???????? ??? ???? ?????? ?? ?????? ?????? ?? ??? ????????? ???? ?? ?????????? ??? ??????? ???? ???? ?????? ???? ??????????? ?? ??????? ?????? 3d ?? ????? ??????? ????????.[73]

???? ???? ???? ???? ?????? 56Fe ??????? ?????? ?????? ?? ??? ??????? ???????? ???? ???? ???? ???????? ??? ??????? ??????? ???? ???? ????????? ?????? ??? ????? ????? ??? ?????? ????? ????? ????? ?????? ?? ?????? ????? ??????? ??????. ???? ????? ??? ?????? ??????? ?????? ????-56 56Fe ?????? ?? ??? ??????? ??????? ?????? ??????? ??????????? ???? ??? ???? ?????? 62Ni ????? ?????? ????? 58Fe.[63][68]

???? ?????? ???? ????? ?? ????? ?????? ???? ????? ???????[de 25] ?????? ?? ??? ?????? ?????? ????? ?? ???? ??? ??? ??????? ???????? ?? ??? ?????? ??????? ??????? ?????? ???? ????? ????? ??? ???? ???? ????????? ???? ?? ????? ??????? ??????? ?? ????? ???? ?? ??? ????.[de 26]

?????? ?? ??????

[???]
????? ????? ?????? ??? ?????? ??????? ??? ?????????.

???? ?????? ????? ??????? ??? ????? ?????? ?????? ??????? ????????? ?? ?????? ????? ????????? ?????? ??????? ????? ??????? ?? ?????? ?????????. ???? ?????? ??? ?????? ??????? ??? ????????? ?? ????? ????? ??????? ??? ???????? ??????? ????????? ???? (α-Fe)? ?????? (γ-Fe)? ????? (δ-Fe). ????? ?????? ????? ?????? ??? ???? ?????? (1538 °?) ????? ?????? ??? ??????? ???? (δ-Fe)? ????? ????? ???? ??????? ??? ??? ????? ????? ????? [?????? 70]? ?????? ???? ????? ?????? ????? ??? 1394 °? ???? ????? ?? ???? ???????? ??? ??????? ????? (γ-Fe)? ????? ????? ???? ??????? ??? ??? ????? ????? ????? [?????? 71] (???? ???? ???? ?????? ????????? ????? 364.7 ???????)? ????? ??? ????? ????? ?????? ?????????. [?????? 72] ??? ????? ????? ??? 910  °? ???? ?????? ????????? ?????? ????? ????? ???????? ??????? ????? ????? (???? ???? ???? ?????? ????????? ????? 286.6 ???????)? ?????? ?????? ????? ???????? ???? (α-Fe)? ?????? ??? ????? ????? ?????? ???????.[?????? 73].[58][74][75] ???? ?????? ?? ????? ???? (α) ?????? ??????? ??? ???? ??? ????? ?????? ????? ?? ??????? ???? ????? ???? ??? ??? 0.021% ????? ??? ???? ????? ??????? 910  °?.[76] ???? ????????? (????? ????? (γ)) ??? ??? ????? ????? ?????? ?????? ???? ??? ????? ?????? ???? ?? ??????? ??? ??? 2.04% ????? ??? ???? ????? ??????? 1146  °?. ???????? ??? ????? ?? ?????? ?? ????? ??????? ??????? ????? ???????? ?? ????? ??????? ???????? ??????? ????????.[77]

?????? ?????? ?????????? ?????? ??? ??? ?????? ????? ?? ????? ????? ????????[78][79] ???? ????? ??????? ?????? ?? ??? ?????.[80] ????? ?????? ?????? ????????? ?? ??????? ???? (α-Fe) ??? ???? ??? ????? ???????? ?????? ??? ?????? ?????? (ε-Fe).[81] ???? ??? ???????? ???? ???? ??? ???? ??? ?????? ?????? ?? ????? (β)? ????? ???? ??? ???? ?????? ???? 50 ?????????? ???? ????? ????? ?????? 1500 ????? ????? ???? ?????? ??? ???? ????? ????? ?????[82] ??? ?? ??? ???????? ??????? ??? ???? ????? ???? ?????? ?????? ??? ????? β ???????? ?? ??? ??????? ??????? ??? ????? ?????? ??????????? ?????? ??? ???? ????? ????.[74]

?????? ???????????

[???]
????????? ??????? ???? ???? ??? ????????? ?????? 1.  ????? ???????? 2.  ????? ??????? (????????)? 3.  ????? ???????? 4.  ????? ????????? 5.  ????? ???????? 6.  ???? ???? (?????) 7.  ????? 8.  ??????? 9.  ???????.[83]

?? ????? ?? ????? ??????? ??? ???? ????? ???? [?????? 74]? ????? ???? 770 °?? ?????? ???? ?????? ???? (α-Fe) ??????????? ?? ????????? ?????? [?????? 75] ??? ????????? ?????? [?????? 76]? ???? ???? ??? ????? ????? ??????? [?????? 77] ???????????? ??? ????????????? ?? ??? ???? ???????? ????? ?????? ????? ??????? ??????? ???? ????? ??? ????? ??? ???????? ????.[84][ar 2] ??? ???? ??? ???????? ????? ???? ??????? ?? ????? ???????? [?????? 78] ?? ????? ??????? 10 ????????.[77] ?? ???? ???? ??? ??????? ??? ?????? ???????????? (dz2 ? dx2 ? y2) ?? ??????? ??? ???? ??????? ???????? ?? ?????? ?????????? ????? ??????? ??? ?????????? ?? ????? ??????? ????????.[74] ???? ??? ????? ??? ????? ?????????? ??????? ???? ??????? ??? ?????? ???????? ?? ??? ????? ????????? ???? ???????? ????????? ????? ?????????? ????? ?????? ??????? ???????. ????? ????? ???? ?????????? ??????? ??? ??????? ??? ?????? ?????????? ??????? ??????? ?? ??? ????? ????? ?????????? ???????? ???? ????? ??? ?????? ??? ???? ??????? ??? ??????? ???????. ??????? ??? ??????? ?? ??????? ???? ?????? ??? ????? ?????????? ?? ?????? ???????? ??? ????????? ?????????? ?????? ??????? ?????????? ?????????? ??????????. ????? ???? ????? ?? ???? ??????? ?? ???? ????????? ???? ?????? ??? ??????? ??? ????? ??????? ???? ?????? ??????????? ?????? ??????? ???? ????? ??? ??????? ??????? ??????? ???? ??? ???? ????? ?????????? ???????? ???? ??????? ????? ?? ?????? ??? ??????? ????.[84]

???? ???? ???????? ????? ???? ??????? ?????? ???????? ????? ?? ????? ?? ????? ???????? ??? ????? ???? ?????????. ???? ??? ?? ????????? ???????? ??? ???? ??? ????????? ?? ????? ??????? ???????? ?? ??????? ?? ???? ??????? ???????? ?? ??????? ??? ????? ????? ?? ????? ????? ???????? ???????? ??? ????????? ??? ????? ??????? ???????? ??????????? ???????? ?????? ???????? ???? ??? ?? ???? ?????? ???? ?????? ?? ????????.[85]

?????? ????????

[???]

??????? ?????? ???????? ?????? ??????? ???????? ??????? ???????? ?? ??????????? ??? ?????? ????? ??????? ?????? ??????? ????? ????? ??????? ??????? ??? ???? ??????? ????? ??? ?????????? ??? ?????? ?????? ??????? ??? ???? ???????? ?????? ??????? ?? ????? ??? ????? ?????????? ????????.[86] ????? ????? ??? ?????????? ??? ???? ???? ??????: ???????? ?????? ?? ????? ?????? ???? ?????? ?? ??????????? ??? ????? ??? ????? ?? ??????? ?? ??? ????? ?????? ?? ???? ???????? ?????? ????? ?? ???? ??????.[87] ????? ??????? ??????? ???? [?????? 79] ??? ????? ????? ??????? ?? ????? ?????? ???? ??? ????? ??? 0.2% ?? ??? ???????? ???? ??? ?????? ???????? ????? ???? ??? ?????? ????? ??? ????? ??????? ??? 0.6% ?????? ?? ??? ???????.[88] ?????? ????? ??????? ??????? (????? 99.99%) ???? ????? ????? ?? 20-30 ??? ?????? ????? ???????.[89]

???????

[???]

???? ????? ????? ?????? ?????? ?????????? ??????:

????? ????? ?????? ????????
  • ?????? ???????? ??? ???? ??? ????? ?? ??????? ?????? ??? 4-5%? ?? ???? ?????? ?? ????? ??? ??????? ????????? ??????????. ??? ???? ???? ????? ????? ?????? ????? (???? ?????) ????????.[de 21] ?????? ???? ??????? ???? ?????? ??? ?? ?????? ??? 1420–1470 ????? ??? ???? ???? ?? ?????????? ??????????? ???? ???? ?????? ??????? ?????? ?????? ????? ??? ????? ?????? ???????? (?????) ?? ??????.[74]
  • ???? ??????? (?? ???? ?????)? ????? ??? ????? ?? ??????? ?????? 2.06%? ?? ???? ????? ???? ?? ???????? ??? ????????? ?????????? ????? ????? ?????? ??? ????? ?????? ????? [?????? 80]. ??? ???? ????? ???? ????? ????? ???????? ??? ??? ??? ???????? ????? ??? ????? ??????.[de 27] ???? ??????? ????? ??????? [?????? 81] ??? ??????? ?? ???? ?????????? [?????? 82]? ??? ????? ?????? Fe3C.[90] ??? ?????? ???? ????? ?? ??? ?????? ??? ????? ??? ?????? ???????? ???? ???????. ????????? ????? ??????? ?????? ?????? ?? ?????? ?? 0.8% ????? ?? ????? ????? ??? 723 °? ??? ???? ????? ?????? ??? ?????? ??? ?????? ??????? ????????? ?? ????????? ??????? ????? ??? ???? ????? ??????? ????? ????????? [?????? 83]. ?? ???? ????? ?? ???? ??????? ?????? ?????? ????? ??? ????? ?? ???????? ?? ???????? ?? ????? ????? ???? ???? ?????????? [?????? 84]? ??? ???? ???? ?????. ???? ?????? ??????? ???????? ?????? ?????? ?????? ????? ??? ??????? ??????????? ?? ??? ?????? ??? ????? ??? ?????.[90] ???? ??????? ????? ???????? [?????? 85] ????? ??? ??????? ??? ???? ????? ????? ??????? ?? ????????? ???? ???? ??? ?????? ????? ?????? ???? ??? ??????? ?????? ???????? ???????? ???????? ????? ????? ?????? ????? ??????? [?????? 86] ???? ???? ???????.[91] ???? ????? ?????? ????? ??????? ??? ???? ???????? ???? ??????? ????? ?????? [?????? 87]? ????? ?????? ???????? ???? ?? ?????????? ?? ??? ????? ??? ???????? ??? ????????? ???? ????? ???? ?? ????? ???????? ????? ????? ????? ?? ???? ?????? ???????.[91]
  • ?????? ???????? ????? ??? ????? ?????? ?? ??????? ???? ?? 0.25%? ?????? ???????? ???? ??? ??????? ?????? ?? ???????? ????? ???? ????? ????? ?????? ???????.[92] ????? ?????? ??????? ????? ?????? ????? ??????? ??? ???? ?????? ?????? ?? ??????? ??????? ???? ?????? ?? ??? ??? ??? ??????? ???????? [?????? 88] ???? ?????? ??????? ?? ?????????? ???????? ??? ???? ??? ????? ?? ??????? ???? ?? 2.0%? ?? ???? ????? ?????? ?? ??????? ??? ???????? ???????? ????????? ??????????.[93]
  • ??????? (?? ???????)? ??? ???? ??? ????? ???? ?? ??????? ??? ??? 2.06%? ??? ???? ?????? ??????? ??? ????? ?? ???? ?????. ???? ??????? ???? ????? ?????? ??????? ?? ????? ??????? ??????? ??? ????? ????????? ????????? ???????? ???? ??? ??????? [?????? 89]? ?? ?????? ??? ????????? [?????? 90].[de 21] ???? ??????? ???????? [?????? 91] ??? ??????? ???????? ?? ??????? ????? ?? ?????? ???? ??? ?????? ??????????? ???????????? ??????? ??????. ??? ????? ?? ???? ??????? ????? ??????? ??????? ?????? ???? ??? ???? ????? ??????? ???????? ?????? ?? ?????? ??????? ??????? ?? ???????? ?? ??? ??????? ??????? ????? ?? ????? ?? ????? ??????? ????? ??????? ????? ???????.[?????? 92].[94]

?????? ??????????

[???]
???? ??????? ???? ??? ????? ???? ????? ??????? ????????
?2 (d10) ?????? ????? ??????? ????? ???????? (???? ??????) Na2[Fe(CO)4]
?1 (d9) ????? ????? ??????? ????? ?????? 2?[Fe2(CO)8]
0 (d8) ????? ??????? ?????? Fe(CO)5
1 (d7) ????? ????? ??????? ???? ?????????? ?????? 2[C5H5Fe(CO)2]
2 (d6) ??????? ?????? ??????? FeSO4? ?????? Fe(C5H5)2
3 (d5) ?????? ?????? ??????? FeCl3? ????? ?????? ??????? Fe2O3
4 (d4) ????? ????? ?????????? ?????? ??????? FeO(BF4)2
5 (d3) ????? ????? ?????? ??????? 3?FeO4
6 (d2) ?????? ?????????? K2FeO4

???? ?????? ?????? ?????????? ??????? ???????? ??????????? ??? ?????? ??? ?????? ????? ????? ????? ????? ???? ????? ?????? ???? ?????? ???????? ??? ?????? ??? ????? ??????? ???????? ??????? ??? ??????? ????? ????????? ????? ???? ??? ???? ???? ?? ???? ???????? ??????? ???????? ??? ???????? ????? ???????.[95]

?????? ?? ??????? ???????? ?????? ??? ?????? ?? ???????? ??? ?????? ???????? ????? ???? ??? ???? ?????? ????? ?????? ??? ???? ?????? ?? ??????? ???????? ????? ?????? ???????? 2+Fe ??????? ??? ??????????:[de 21]

????? ?? ?????? ?? ??? ??????? ???????? ????? ??????? ????????? ????? ????? ???? ????? ?????? ??????? ?????? ?????? ?? ??? ?????????????.[74] ?????? ?????? ?? ?????? ????? ??? ????? ??????? ?????? ????? ?? ????? ????????? ?????? ??????? ????????????? ????? ???? ?????? ?????? ?????. ??? ???? ??????? ?????? ??????? ???? ?????? ????? ???????? ?????? ????? ??? ?????? ????????? ??????? ?? ??? ????? ?? ?????? ??????? ??? ????? ????? ???????. ??? ????? ?????? ?? ?????? ?????? ?????? ????? ?? ????? ?????? ??????? ???????? Fe3O4. ??? ????? ?? ???? ???? ???????? ?? ?????? ?????? ?? ????? ????? ?? ??????? ????? ????? ?? ?????? ??????? ?????? ?? ?????? ?????? ??????.[96]

?????? ????????

[???]
????? ?????? [?????? 93] ??????

????? ??? ?????? ?????? ?????? ?? ???????? ??? ???? ???????. ???? ??? ??? ??? ???????? ??????? ?????? ??????? ?? ????? ??????:[74]

Fe2+ + 2 e? is in equilibrium with Fe E0 = ?0.447 V
Fe3+ + 3 e? is in equilibrium with Fe E0 = ?0.037 V
FeO42- + 8 H+ + 3 e? is in equilibrium with Fe3+ + 4 H2O E0 = +2.20 V

???? ????? ???????? (?? ????????) ?????? ??? ???? ?????? ????? ??????? +6? ????? ??? ??????? ?? ??????? ???? ???? ?????? ??? ?? ???? ?????? ??????? ?????? ??? ????????? ???????? ?? ?????? ?? ????? ????????? ????????? ??? ???? ????? ??????? ???? ???? ????? ?? ??????? ???????? ?? ???????.[97]

????? ?? ???? ???? ?????? ??????? 3+Fe ?? ???????? ??? ???? ????? ?????? 3+[Fe(H2O)6]? ??????? ???? ?????????? ?? ??? ??????? ?? ????? pH ????? ?? ????? ?????? ???????????? ???? ?? ?????? 3+[Fe(H2O)6] ??? ?????? 2+[Fe(H2O)5(OH)]? ?? ??? ?????? +[Fe(H2O)4(OH)2]? ??? ?????? ?????? 2+4[Fe(H2O)4(OH)] ????? ?? ??????? ??????? ????????? ???.[98]

????????? ?? ???? ???? ?????? ??????? ????? ???????? 2+[Fe(H2O)6] ?? ????? ?????? ?????? ?? ???????? ??????? ??????? ?? ???? ????? ?? ?????? ?????? ??????? ??????? ?? ??? ????? ????? ????????? ?? ?????? ????? ????? ???????? ???? ???? ????? ????? ?????? ??????? ?????? ??????? FeCO3. ????? ?????? ?? ????? ????? ??????? ???? ?????? ??????????? ?? ?????? ????? ??? ??????? ????? ????? ?? ?????? ???????? ???? ????? ?? ?????? ?????? ??????? ??? ??????? ??????? ????? ?????? Fe2O3 ?? ?????.[99]

???????? ??????????

[???]
????? ?????? ??????? FeO (????? ????????)
????? ?????? ??????? Fe2O3 (????? ????????)
????? ?????? ??????? ???????? Fe3O4 (????? ?????? ??????????)

???? ???? ?????? ??? 24 ?????????? ????? ?????? ??? ??????? ?????????? Ar;3d64s2? ????? ???? ??????????? 3d ? 4s ???????? ???? ????? ?? ???? ????? ???? ?????? ?? ???????????.[90] ?????? ?? ???? ??????? ????? ????? ???????? ?? ??????? ???? +2 ?+3? ???? ????????? ?? ???????? ?????????? ??? ???? ??????? +2 ????? ?????? ??????? ????????? ??? ???? ??????? +3 ???? ??????? ????????. ???? ?????? ??????? ?????? ?? ????????? ??????? ?? ???? ?? ??????? ??????? ?????????? ???????.[de 21][100] ?? ???? ????? ?????? ?????? ????? ?? ????? ??????? ???????? ?????? ????? ????? ??? ???? ??????? +6 ?? ????? ?????? ?????????? [?????? 94] ??????? K2FeO4? ???? ????? ??????? ?????? ?? ??? ????? ????? ??? ????? ??????.[101] ???? ???? ?? ??????? ?????? ???????? ????? ?????? ???? ???? ????? ?????? ??? +1 ?? 0 ?? ?1 ?? ??? ?2. ?????? ?? ??????? ???? ????? ?????? ?????? ???????? ????? ??????? ????????? ??? ????? ??????? ???????.[102] ???? ???? ?? ????????? ?????? ??????? [?????? 95] ???????? ??? ????? ?? ?????? ??????? ????????? ????? ?? ????? ?? ????????? ?? ???? ???? ?????? Fe4[Fe(CN)6]3?[de 21] ????? ??? ???? ????????? ?????? ?? ??????? ???????.[103]

?????????

[???]
???????? ????????????

????? ?????? ????? ?? ?????? ?????? ????????? ?????? ?????? ????? ?????? ??????? FeO (????? ????????)? ?????? ?????? ??????? Fe2O3 (????? ????????)? ?????? ?????? ??????? ???????? Fe3O4 (????? ?????? ??????????)? ?? ???? ???? ?? ??? ???????? ??? ?????????.[104] ?? ?????? ????? ????? ????????? ?? ???????? ?? ?????? ????????? ?????? ??????? ?????? ??????? FeC2O4? ??? ????? ?? ??? ????? ????? ??? ?????? ??? ???? ????? ??????? ?? ?? ????? ???? ?? ??????. ???? ????? ???????? ??? ?????? ???????? ?? ??? ???? ??? ????? ??????? ??? ????? ?????? ????? ?????? ????? ?? ????????? ??? ???? ??????? ??? ???? ?????? ????????? ??????????.[?????? 96] ???? ????? ?????? ??????? ???????? ??? ?????? ?? ????? ??????? +2 ? +3? ??? ?????? ??????? ?? ?????? ???????? ?? ?????? ???? ??? ???? ???? ?????????. ??? ???? ?? ?????? ??? ??? ?????? ????? ?????. ???? ???????? ???????? ???????? ???????? ?? ????? ??????? ????? ???? ?? ????? ?????? ?????? ?? ??????? ???????? ??? ???????? ?? ????? ???? ??????? ?????? ??????? ?????????? ??? ???? ???????. ???? ?????? ????? ????? ?????? ??????? FeO2? ??? ????? ??? ???? ??????.[105] ?? ???? ???? ??????? ?? ?????? ?????????? ???? ??? ????? ?? ?????????? ?? ??????? ???? ?????? ??????? ??? ?????? ??? ????? ????? ???????? ?????? ?? ???? ?? ????? ?????? ???????? ????? ???? ????? ????? ??????? [?????? 97]? ????? ?????? ??????? ?????? ??????? ??????? ????? ?? ???????? ?? ???? ?????? ?? ??????.[de 28]

????? ????? ????????? ?????? ??????? FeO(OH) ??? ?????? ?????????????? ????? ???? ?? ????? ??? ?????? ????? ?????? ???????. ???? ??? ??????? ?? ??????? ??? ??????? ?????? ?? ????? ???? ?? ???? ???????? ??????? ?? ????? ????? ?? ???? ???????????? [?????? 98]. ???? ?? ?????? ??????? ??? ???? ?????????? [?????? 99] ?? ????? ????????? ?????? ???????? ????? ?????? ??? ??????? ??? ????? ?????? ???????.[de 29]

???????????

???? ???? ??????? ?????? ??????? ?? ??????? ??? ???? ???? ????????[?????? 100]? ????? ???? ?????? ?????? ????? ?????? ?? ??? ?????????? ???? ???? ????? ??????? ?????? ????? ?????.[de 21] ??????? ?????? ?????????? FeS2 ??? ?????? ??????? ???? ??? ?????? 2+Fe ?2-S2 ?????? ??? ???? ??????? ?????? ??? ??? ???? ?????? ????????.[104]

?????????

???? ??????? ?????? ??????? ???????? ?? ????????? ?????????? ????????. ???????? ??? ??????? ???????? ???????? FeX2 (FeF2 ?FeCl2 ?FeBr2 ?FeI2) ????? ?????? ?? ?????? ???? ?????? ?? ????? ????? ?????????? HX ????????:[de 21]

?????? ?????? ??????? ????? ????????
??????? ?????? ??????? ????? ????????

???? ??????? ???????? FeX3 (FeF3 ?FeCl3 ?FeBr3 ?FeI3) ????????? ????? ?? ??????? ??????? ??? ???? ?????? ?????????? ???????:[106]

????? ??? ????????? ????? ?? ?????? ?????? ??????? FeCl3? ????? ???? ???????? ?? ????? ?????? ??????.

???? ????? ????? ???????? ????? ??????? ??? ??? ?????? ??????????????? ???? ???? ?????? ???????? ????? 3+Fe? ??????? ?????????? ???????? ????? ??????? ?I.[106]

?????? ?? ??? ???? ????? ??? ??????? ??? ????? ??????? ???? ?? ????? ????? ??????? ?????? ?? ????? ?????? ????? ??????? ?? ??? ?? ??????? ??????? ???? ??? ???? ????? ???? ?20 °?? ?????? ?? ???????? ??????.[106] ????????? ???? ??????? ????? ????????? ?? ??? ??????? ?????????? ?? ??????? ???????.[107][108]

?????????

????? ????? ??????? ?????? ??????? FeSO4 ?????? ???? ????? ??????? ???? ????? ????? ?????? ???????? ??? ???? ????? ????. ?? ???? ????? ???? ?????? ????? ??????? ?????? ??????? Fe2(SO4)3 ??? ??? ????? ????? ??? ???? ?????? ???? ????? ??????. ???????? ?????? ??????? ???????? ?????? ???? ???????? ??????? ?????? ?? ?????? ???????.

????? ????

?????? ???? ????? ?? ??????? ?????????? ?????????? ?????????? ???? ??? ???? ??????: ??????? (????? ?????? ??????? Fe(NO3)2 ?????? ?????? ??????? Fe(NO3)3)? ????????? (?????? ?????? ??????? Fe3(PO4)2 ??????? ?????? ??????? FePO4). ??? ???? ?????? ??? ????? ??? ???? ??????? ????????? ??????? ??????? NH4)2Fe(SO4)2.6H2O)? ???????? ???? ???? ????? ??? ???? ??????? ???? ?? ????????? ????? ??? ???? ??????? ????????? ??????? ??????? NH4Fe(SO4)2.12H2O. ??? ?????? ???? ????? ?????? ??????? ??? ??????? ??????? ??? ????? ?????? ???????.[de 21]

???????? ?????????

[???]
???? ???? ??????
??????? ??????? ????? ??? ???????.

????? ?????? ??????????? ???????? ?????? ??? ???? ??? ????? ???? ?????? ?? ????????? ?????????? ?? ??????? ??????? ??? ??? ??????? ????? ????? ???????? [?????? 101] 3?[FeCl6]? ??? ???? ?????? ??????? ??? ?? ??? ?????? ?????? 6? ??? ?????? ?? ???? ??????? ?????? ????? (????? ???????) ????? ????? ????????[?????? 102].[109][110] ???? ??????? ?????? ??????? ???????? ?? ?????? ???????? ?? ???? ??????? ?????? ?????? ??????? ?????????? ??????? ???? ?????? ????? ?? ??? ??????? ???? ???????. ?? ?? ???? ??????? ?????? ??????? ?? ?????????? ??????????? ??? ?????? ?????? ????????? ?? ??????? ?????? ???????? ??????? ?? ?????? ?? ???????? ???????. ???? ??????? ?????? ??????? ??? ??????? Fe–O ??????? ?????? ??????? ?? ?????? ?? ???????? ????? ?? ????????? ?? ?????????? ????? ?? ????? ?? ?????? ?????? ???????? ????? ?? ???????? ?? ?????? ?????? ???????? ?? ??????? ????? ??????? ?? ??? ?????? ????.[111]

?? ??? ????????? ?? ????????? ?????????? ??????? ???? ??????? ?????? ??????? ???????? ?????? ?????????? ????? ????? 2? [FeF5(H2O)] ???? ????? ?? ??????? ???????. ?? ?????? ????????? ???????? ??????? ?????? ????? ??? ????? ??????? ????? ??????? ??? ?? ????? ?? ????? ? [FeCl4]? ???????? ??????? ?????? ? [FeBr4] ?? [FeI4] ?????? ??? ?????? ???????. ??? ?? ????? ?? ???????? ??????? ????? ???? ??????? ?????? ??????? ??? ???? ??????? ?????? [?????? 103] ???????????? ???? ???? ??????? ??? ???????? ????? ?? ???? ??????? ?????????? ??????? ??? ????????. ?? ??????? ??? ??????? ?????? ??????? ?????? ????? ??????? ????? 3? [Fe(CN)6]? ????? ????? ?????? ?????? ???????? ???????? ???? ????? ??? ????? ???? ???? ??? ????? ?? ????? ?????? ??????? 4?[Fe(CN)6] ?????? ?? ????? ???? ???? ???????[111] ????? ?? ????? ?????? ?????????? ???? ????? ?????? ?? ?????? ??????.[112] ???? ???? ???? ?????? (??????????? ????????) ?? ??????? ??? ??????? ?????? ????????? ??????? ??? ?????? ??????? ???????? ?? ??????? ??? ????? ?? ?????? Fe4 [Fe(CN)6]3? ??????? ?? ????? ??? ?????? ??????? ?? ????????? ?????????? K4 [Fe(CN)6].[de 21] ??? ?????? ??? ??????? ?????? ??????? ????????? ???? ????????? ??????? ?? ???????? ?? ?????? ???????? ?? ???? ??? ??????? ??? ?????? ???????? ????? ??????? ?? ??? ?????? ???? pH ????? ???? ????? ?????????? ???????? ?? ???????.[112]

?????? ??????? ?????? ??????? ??????? ??? ?????? ?????? ???? ?????? ??????? ???????? ???? ???? ??????? ???? ??????? ??????? [?????? 104] ?? ?????? ??????? ?????? [?????? 105] ????? ??? ?????? 2?1-????? (????? ????? ???????) ??????? (dppe) ?? ??????.[113][114] ???? ???? ????? ??????? [?????? 106] ??? ???? ?????? ?? ?????????? ??? ???? ?????? ??????? ????????.[?????? 107][111]

???????? ??????? ???????

[???]
?????? ??????? ?????????? ??? ???? ????? ???

????? ?????? ?????? ??????? ?????? ????????? ??????? ????? ?????? ??????? ??? ????? ???????? ??? ?????? ???????? ??????. ?? ????? ????????? ??????????? ????????? [?????? 108] ???? ???????? [?????? 109] ?? ??????? ???????? ??? ??????? ?????? ??????? ????? ?????????? ??????? Fe(C5H5)2 ????? ?????? ??????? ?????? ??? ???? ??? ???? ???? ?????? ???????? ??? ??????? ?? ????? ???? ????????????. ????? ??? ??????? ??? 1951?[115] ????? ??? ???????? ??? ??? ????? ?????? ?? ???????? ?? ??? ????????[116] ??? ??????[117][118] ????? ?? ???? ????????? ??????? ??????? ????? ????? ?????? ???? ?????????????.[?????? 110][119]

?? ??????? ????????? ????? ??? ??????? ?????? ??????? ????? ????? ??????? ?????? Fe(CO)5? ????? ????? ??? ???? ?????? ???????? ???????? ???? ????? ????? ???? ?????? ?? ????? ????? ???????. ???????? ??????? ?? ??? ????? ????? ?????? ???????????[?????? 111] ??? ???? ??????? ?????? ?????? ?????? ????????? ??????????. ???? ??????? ??????? ?????? Fe(CO)5 ??????? ???? ??? ???? ???? ??????? ????? ?????? [?????? 112] Fe3(CO)12? ??? ???? ??? ???? ????? ???? ?? ????? ????????. ???? ???? ?????? [?????? 113] ?? ??????? ??????? ?? ???????? ???????? ??? ?????? ????????? ?? ?????? ????? ??????? ????? ???????? Na2[Fe(CO)4]? ????? ??? ???? ?????? ????? ??????? (-2) ???????? ??? ???? ????? ???? ??????? (+1) ??????? ????? ?????? ?? ????? ????? ????? ??????? ???? ?????????? ?????? 2[C5H5Fe(CO)2].[120] ???????? ????????? ??????? ??? ???? ???? ?????? ?? ???? ???????? ????? ?? ????? ?? ????? ??????????[?????? 114] ????????? ??????? ?? ??? ????? ?????????.[121]

??????? ?????????

[???]

???? ???? ?? ?????? ??????? ??????? ?????????? ????????? ????? ?? ???????[de 30] ????:

????? ????? ???????? ??? ?????????????

?????? ??? ????????????? ????? ?????? ?????? ??????? ?? ??????? ?????? ??????? ?? ??? ???? ????:[de 31]

????? ?????? ???? ?????? ?????? ??????? (????) ??? ???? ?????? ?? ??????????? (????).
????? ????? ???????? ???????????

???? ????? ?? ?????? ?????? ??????? ???????? ???? ??????????? (??????? ????? ???? ????????? [?????? 115])? ??? ?????? ????? ????????? ?????? ???????? ?? ????? ?????? ??????:

???? ?? ???? ????? ?? ??? ??????? ?? ??? ???? ?????? ?? ???????? ?? ??????????? ?? ??????.[de 32]

????? ????? ????? ???? ??????

???? ????? ?????? ??????? ?? ????? ????????? ?????????? ????? ????:

??? ???? ???? ????? ????? ?????? ??????? ?? ????? ????????? ??????????:

????? ?? ??? ?????????? ??? ????? ??? ???? ???? ??????? ?? ???? ???? ????? ??????? ??? ????????:[de 33]

?????

[???]

??? ???? ???????? ???? ????? ?????? ????? ????? ?????? ?? ????? ???? ?????? ????? ?? ???? ?? ??? ??????? ????? ????? ?? ???? ???????? ???? ????? ????? ?????? ?? ???????? ???????.[74] ???? ????????? ?????????? ?????????? ?? ????? ??? ?????? ??? ????? ??????:[122]

????????:

????????:

??????? ????????:

??????? ??????? ?? ?????? ?????? ??????? ??????? ??????????? ???????? ?? ????? ????? ????????? ?????? ??????? Fe(OH)3? ????? ?????? ??? ????? ????????? ?????? ??????? FeO(OH) ????????:

????? ???? ?? ?????? ??? ?????? ?????? ??????? ???????? ????????:

???????? ?????? ???? ?? ????? ??? ???? ?????? ?? ?????? ?????? ??????? ???????? ??? ?????? ??????:

??????? ????? ????? ???? ????? ?????? ????? ??????? ?? ??????? [?????? 116] ?? ??????? [?????? 117] ?? ??????? ????? ?? ??????? ?? ?? ???? ????? ????? ???????. ???? ??? ??????? ??? ????? ?????? ?? ????? ???? ?? ???? ??? ??? ??????? ?? ????????? ?? ?? ???? ??????? ????????.[122]

?????? ???????? ?????? 1-??????-3-???? ??? ???????? ???????? ?? ????? ??????.

????? ??????

[???]

??? ?????? ????? ???? ???????? ???? ?? ??????? ???????? ????? ?????? ???? ??? ?????? ??????? ???????? ?? ??????? ???? ?? ??????? ????????? ??? ??????? ??????? ??????? ??????? ??? ???? ????? ?? ?????? ?????? ??????? ??? ??? ??????.[de 34] ??? ????????? ???????? ?? ????? ?????? ??????? ?? 1-??????-3-??? [?????? 118]?[123] ??? ????? ?????? ??? ???? ?? ????? ???? ?? ?????? ?????? ?????.[de 35] ???? ???? ??????? ???? ?? ?????????? ??????????? ????? ???? ?? ??? ????? ????????? [?????? 119].[de 36] ???? ????? ?????? ??? ??? ???? ??? ?????? ??? ????? ???? ????? ??? ?????? ?????? ???????.[de 36]

????? ??????

[???]

?????? ??????? ???????? ????? ??????.[124][125] ?? ????? ???????? ????????? ????????? ?? ???? ?? ?????????? ?? ????? ???????????? ??? ????? ?????? ?? ??????? ????? ?????????? ???????. ??? ????? ?????????? ??????? ??? ?????? ?? ??????? ??? ?????? ???????? ?????????[126] ????? ?? ??????? ?????? ????????? ?????????.[127] ???? ????? ????????? ?? ?????? ??? ????? ?????? ??????? ?? ?????? ?????? ???????.[128]

???? ???? ????? ??????? ?? ???????????? (???? ????)

???? ???????? ????? [?????? 120] ???? ??????? ??? ?????????? ??????? ??? ?????? ?? ??? ???????? ?? ?? ???????????? [?????? 121] (???? ????) ????????????? [?????? 122] ????????? P450 [?????? 123].[126] ????? ??? ?????????? ?? ??? ??????? ????? ????????? ???? ???????????.[127] ?? ??????? ??? ?????????? ???????? [?????? 124] ??????? ??? ?????? ??? ?? ?????????? ????????????? [?????? 125]?[127] ??? ???? ???? ???? ?? ????????? ??????? ??????? ??? ?????? ??? ????????? [?????? 126]?[129][130] ????????????? [?????? 127]?[131] ???????? ??? ??????? ?????? ????? ????????? ??????[?????? 128]?[132] ????????????? [?????? 129].[127] ??? ?????? ????? ?????? ?????? ??????? ??????? ???????? ????????? ?? ??? ???????? (???? ?????? ???????) ???? ?????????? ?? ??????? ????????? ??????? ????? ???? ???????? ?? ???? ?????? ???? ??? ??? ?????? ???????? ???? ?????? ??? ???? ?????? ??? ?? ?????? ??? ??????.[126] ??????? ??? ????????? ??????? ??? ????? ????? ???? ?????? ?????? [?????? 130].[133][134]

??? ???????

[???]

???? ??? ????? ???? ?????? ??? 0.005% (???? ??????) ?? ???? ??????? ???? ????? ????? ????? ??????? ????? ????? ???? ????? ??? ???????? ??? ???? ??????????? ??? ????? ???? ????? ??? ????? ??? ????? ???????? ???? ?? ?????? ?????? ?????? ?? ??????[127] ???? ????? ???? ????? ???????????? ?? ??? ?????? ??? ????? ?????? ???.[135]

??? ????? ??? ????? ?????? ???? ??? ???????? ?????? ????? ?????? ????? ?????[126][136] ?????? ?????? ???????????? [?????? 131] ????? ??????? ?? ???? ?? ???? ????????? ?? ?????? ?????? ??????? ?? ????? ?????? ????? ?????? ?? ???? ???? ??? ???????.[126][137] ???? ?????? ?????????? ??? ???? ???????? 3+Fe ?? ???? ????? ???? ????? ????? [?????? 132]? ????? ????? ?? ???? ??????? ????? ????? ??????? ???????? ??? ???? ????? ??????? ????????? [?????? 133] ????? ??? ?????? ?????? ???????? ?? ??????. ??????? ?????? ?? ???????????? ?? ???? ?????? ?? ???????? ??? ???????? ??????? ????????????? ???? ??? ???????? [?????? 134].[127]

???? ??? ?? ??????? ??????????? ??? ??? ????? ????????? (??? ???????? ?????? ??????) ?? ????? ??????? ????? ?????????? ??????. ????? ???? ???? ?????? ???????? ?????? ????????? ?? ??????.[138]

????? ???????????? (???? ????) ?? ??? ???????? ?? ????? ???? ??????? ??????? ????? ??????? ????? ???? ???????? ?? ???????? ?? ??????? ??? ???????? ??? ?????? ???? ??? ?????????? ????? ?????? ??? ??? ?????? ???? ?? ??? ??????? ??????????? ???????? ???????? ??????.[126] ????? ???????????? ?? ????? ????? ??????? ?????? ?? ????? ???????? ?????? ??? ??????? ??? ???? ????? ????????? ?????? ??? ???????? ??? ?????? ?? ??????.[127] ??? ?????? ?? ???????????? ?? ???? ?? ???? ????? ?? ?????? ????? ?????? ??? ????? ???????? ???? ???? ?????? ?????? ??? ????? ??? ????? ???????: ???? ????? ?? ????? ??????? ?? ???? ??????????? ?????? ????? ?? ???? ??????? ?? ???? ????????? ?? ????? ??????? ????????? ?????? ????????? ?? ????? ?????? ?? ???????? ??????? ??????? ?????? ????? ?????? ??????? ?? ??? ???????? ?? ???? ????????.[127] ????? ?? ????? ???????????? ?? ????????? ????? ???? ????? ?????????? ????? ???????? (?????? ??????????)[?????? 135] ???? ?????? ???????? 2+Fe ?? ???? ????? ?? ???? ????? ???????? ????? ????? ??????? [?????? 136]? ???? ???? ?? ?????? ??????? ???? ?????? ?? ????? ???? ?????????? ?????? ?????? ???? ????? ??? ???? ?????? ???????? ??????? ??????? 55 ???????? ???????? ??? ????? ????? ??????? ??????? ???? ????? ??? ??? ?????? ?????? ??????? ???????? ??? ???????? ?? ??????? ?? ???????? ???? ???.[127]

????? ????? ???????????? ????? ???????? ???? ??????? ???? ?????????? ?????? ?????? ?????? ????? ??? ????? ??? ???????? ?????? ????? ????????? ????? ????? ????? ?????????? ???. ???? ???? ???? ???????? 2+Fe ?? ???? ????? ???????? ????? ????? ??????? [?????? 137]? ???? ????? ?? ????? ???? ????? ??????? ?????? 20%? ???? ????? ?? ?????? ??? ?????? ?? ????? ???? ??????????? ??????? ???? ????? ??????? ?????? ??????? ???? ????.[127] ???????? ??? ???? ???? ??????? ???????????? ???????? ????? ?? ????? ???? ????????? ???? ???? ????? ??????? Fe–O–O ????? 120°? ???? ????? ????? ????? ????? ??? Fe–O–Fe ?? Fe–O2–Fe? ????? ?? ????? ?????? ??? ???? ?????? ????????? ?? ??? ????? ???????? ??? ??????? ?? ??? ??????? ????? ?????? ????????????? ????? ???? ????? ??? ????? ??? ????? ???? ?? ???????????? ??????? ???? ???? ???????? ???? ????????? ??????? ????? ???? ???????????? ????? ???????? ??????? ???????? ???? ????? ???? ???????? ??????? ?????? ????.[127] ?? ???? ????? ???? ???? ??????????? ???? ??? ?????? ??? ?????? ??????? ?? ???? ????? ????? ?????? ???????? ????? ??????. ???? ???? ???????????? ???? ??? ?????? ????????? ?? ??????? ?????? ????? ?????? ?? ???????? ????????? ?? ???????? ???? ???????? ???? ????? ???? ???????? ???? ????? ?? ??? ???? ???????????? ????? ?????? ???? ?? ???? ????? ?????? ?? ???????? ????????? ?? ????? ???????.[127] ????? ???? ????? ????? ??????? ?? ?????? ??? ??????? ?? ???? ???????????? ??? ????????? ??? ?? ????? ?? ????? ???.[127] ???? ??? ???????? ??? ??????? ?????? ??? ???????? ??? ????? ????? ??????? CO ?????? ?????? ???????? PF3? ????? ???? ??????? ??? ???????? ??? ???????????? ???? ???? ?? ?????? ????????? ???? ????? ??? ????? ?????? ??? ???????? ??? ????? ?????. ???? ???? ???????????? ??? ??????? ?? ????? ????? ??????? ???? ??????? ??????????. [?????? 138] ???? ???????? ?????????? ??? ??????? ???? ??? ???? ?? ?????? ??????? ??????????? ???????? ?????????? ?????? ????? ?????? ?????? ???? ???????? ????????? ?? ????? ????? ?? ????????? ???? ???? ?? ??? ?????????? ?????? ???? ???? ???? ????????. ???? ?????? ??? ???????? ?????????? ?? ???? ???? ??????? ?????? ???? ??? ???? ??????? ?????? ?????? ??? +2 ?+3.[127] ???? ?????????? ???????? ????????? ??? ????? ?????? ??? ????? ?? ?????? ???????? ?????????? ?????????. ???? ??? ?????????? ??? ??????? ??????? ?? ????? ?????? ????????? ???? ?? ???? ??????? ??? ??? ??? ????? ?????? ???? ??? ???? ?????. ???? ???? ??? ?????????? ??? ????????????? ??????? ??? ???? ???? ????? ??????? ??? ???? ????? ?? ???????.[127]

??? ???????? ??????

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????? ???????? ????? ?? ??? ???????? ??? ?????????? ??? ?? ????? ??? ???????. ??????? ???????? ????? ?????? ??? ????? ??????? ??????? ???? ?? ???? ??????? ??? ????? ?????????? (???????) ????????????? (?????????)? ???? ?????? ???? ?? ????? ???? ?? ????????? ??????? ???? ????????? ???? ??? ???? ??????????? ?? ????? ????? ??????????? ??? ???? ??????? ??????? ?? ??? ????? ????? ????????? ???????.[139] ????? ?????? ?????? ???????? ?? ???????? ?????? ??????? ???????? ?????? ?? ???? ???????? ?? ?????? ?? ??? ???????? 3+Fe? ???????? ??? ???????? 2+Fe? ?? ???????.[140] ?? ?????? ????? ?? ??? ??????? ????? ????? ???????? ?? ????? ??? ?????? ?? ?????? ??? ?????? ??????? ???????.[de 35] ???? ?????? ?????? ????? ??????? ???????? (??? ??? ????? ????????? [?????? 139] ?????? ??????)? ????????? (??? ???????? ????????? [?????? 140])? ????? ??????? ??????? ??????? [?????? 141] (?????? ?? ???? ?????? ????? ?????? [?????? 142]).[de 35] ???? ?????? ?????? ??????? ?? ?????? ??? ?? ????? ???????? ???????? ?????? ??????????? ?? ??? ?????? ????? ????? ???????.[141]

??????? ??????

[???]

?????? ???? ???????? ?? ??????? ??? ??????? ???????? ???????? ??????? ??????? ?? ?????? ??? ?? ?????? ??????? ????? ??????? ?????? ??????? ?????????? ?????????? ????? ?? ?????? ???? ?????.[126] ?? ??? ??????? ?????? ????? ????? ?????? ??????? ??? ?? ????? ?? ????????.[142] ???? ?? ???????? ??? ?????? ??? ????????? ???????? ??? ???? ??????? ?? ??????? ?????? ???????.[143][144] ?????? ?????? ?????? ???? ???? ?????? ????? ???? ????????????? ?? ??????? ?????????[145] ??? ?????????.[146]

???????? ????????

[???]
???? ??????? ??????? ??? ??????? ??????

??????? ?????????? ??????? ???? [?????? 143] ?? ???????? ???????? ????????? (?????? ??? ??? ?????? ???????? ?????) [?????? 144] ????? ?????? ???????? [?????? 145] ?? ?????? ?? ??? 2001?[126] ???? ?????? ?????? 7.9 ??/????? ??????? ????? ??????? ??? 14-18 ???? ??????? 8.1 ??/????? ????? ??????? ??? 19-50? ??????? 5.0 ??/????? ????? ?? ???? ???? ?????? ??????? ???????? [?????? 146] ??????? ??? ????? 27 ??/?????? ????????? ?????? 9 ??/?????? ??? ??????? ??????? ????? ??????? ??? 1-3 ??? ?????? 7 ??/?????? ???? 4-8 ??? ?????? 10 ??/?????? ???? 9-13 ??? ?????? 8 ??/?????? ???? ??????? ?????? ??????? ????? ?????? ???????? ?????? 6.0 ??/????? ??? ?????? ??????? 19 ???? ???????? ?????? ???????? ?????? 8.0 ??/?????? ?? ????? ??? ??????? ?????? ??????? [?????? 147] ??????? ?????? ?? ????? 45 ??/?????.[147] ???? ?????? ????????? ?????? ??????? [?????? 148] ?????? ????? ?????? ??? ?? ????? ?? ???????? ????????.[148][149]

?? ????? ??????? ?????? ??? ??????? ??????? ?? ??? ??????? ????? ???? ?????.[150] ?? ???? ????? ?? ????? ?????????? ????? ?????? ??? ????? ??????? ?????? ?????.[151] ???? ???? ?????? ??????? [?????? 149] ??????? ?????? ??? ??????? ?????? ?? ??????? ????????? ??? ?????? ????????? ???????? ?? ???????? ???????? ????? 18  ??.[152][153]

??? ??????

[???]

???? ??? ?????? (?? ??? ??????) [?????? 150] ??? ???? ????? ??? ??????? ?????? ?? ??????.[154][155] ???? ??? ????? ????? ?? ?????? ?????? ?????? ?? ????? ??? ???? ????? ?????? ???? ????? ?? ???? ????? ??? ???? ??? ???? [?????? 151] ?? ???????? ????? ?? ?????? ?? ??? ??? ???????? ??? ??? ???? ?????? ?? ??? ?????? [?????? 152]? ????? ?????? ???? ???? ???? ???? ?? ????? ???? ???????? ??????? ??? ????? ?? ???????????? (???? ????).[156] ??????? ????? ??????? ???? ?????? ?? ??? ?????? ????? ????? ??? ????? ?? ?????? ??????? ?????? ??? ??? ??? ???????? ???? ?? ?????? ??? ????? ????? ??? ?????? ????? ??????? ????????? ????? ?????? ?????? ?????? ??? ???????.[157]

??? ??????

[???]

?????? ????? ?????? ?? ??????? ???? ????? ????? ????? ??? ????????? ???? ??? ????? ?????? ???? ??????? ??? ?????? ??? ???? ????? ??? ??????? ?????? ?????? ???? ?????? ??????? ???????? ???????? ????????? ????????? ??????? ???? ??? ????? ?????? ?? ????? ???? ???? ??????? ?????? ???.[158] ???? ??? ????? ???? ?? ??? ????? ?????? ????? ?????? ???? ?? ?????? ??????? ????? ????? ??? ??????? ??? ??????? ?? ????? ?????? ?????????? [?????? 153]? ??? ????? ??????? ????? ?? ??? ???? ?????? ??? ???? ??????? ??? ????????.[159] ??????? ???? ????? ??????? ????? ?? ?????? ????? ??? ???? ???? ??? ?????? [?????? 154]? ????? ???? ????? ??? ???????? ?????? ??????? [?????? 155]?[126] ??? ???? ??? ???? ????????? ????? ????? ?? 1% ?? ??????? ???? ?????? ?? ??? ????? ??????? ?????? ????? ????? ??????? ??????.[160]

?????? ???????

[???]

????? ??? ?????? ?????? ?? ?????? ??? ??????? ??????? ??????? ?????? ????? [?????? 156] ?? ?????? ???? ????? ??? ????? ???????? ?? ????????????? ???? ???? ?????? ????????? ?????? ????? ???? ?? ????? ?????? ???? ?????? ????? ????? ?? ???? ???? ??????? ??????? [?????? 157]. ???? ??? ?????? ????? ???? ??????? ?????? ????????? ????????? ?? ???????????? ??????? ?? ???????? ??????? ????? ???? ?????? ???? ????? ????? ?????? ??????? ???????? ???????? ?? ????? ??????? ???? ?? ???? ???? ????? ?????? ??? ????? ????????? ??????? [?????? 158]?[de 35] ????? ?????? ?????????? [?????? 159] ??????? ????????? ?????? [?????? 160] ???????? ??????? ???????? ?????? [?????? 161]? ???????? ??? ???????? ????????? ???? ??????.[161] [ar 3]

???? ???? ??????? ??????? ????? ?????? ?????? ?????? 20 ???????? ??? ???????? ?? ??? ?????? ????? ?????? ???????? 60 ???????? ??? ???????? ?? ??? ????? ????? ???????.[162] ????? ???????? ??????? ???????? ?????? ??? ??????? ??? ???? ??????? ?? ??????[162] ???? ????? ?? ?? ?????? ??????? ?????? ??????? ?? ????? ?????? ????? 40  ????????/?????.[163] ??? ???? ???? ??????? ??????? ???? ?????? ???? ???????? ??? ???????????? [?????? 162]? ????? ???? ??? ??? ?????? ?????? ?? ?????.[161][164]

??????? ???????

[???]

???? ???? ???? ??? ??????? ?????? ?? ????? ???? ?????? ???????? ???? ????? ??? ???????? ??? ??????[165] ???? ????????????[?????? 163] ???? ????????? [?????? 164].[de 35] ????? ??? ??????? ??? ????????? ????????? ?? ?????? ?? ????? ?????? ???? ?? ???? ????? ?? ?????? ?????? ?????? ??? ???????? ??????? ??? ???????? ?? ??? ?????? [?????? 165]?[166] ???? ?? ???? ???? ??????? ?????? ?? ??????? ?????? ????? ???????? ?????? ?? ??? ??? ????????.[167]

??????? ??????? ?? ???? ??? ?????? ?????? ?? ?????? ???? ???? ????? ?????? ?? ????????? ??? ???????.[168] ??? ???? ???????? ??????? ???? ???????? ?????? ????????? ???? ??? ?? ????? ???? ??? ?????? ???? ????? ???? ?? ?????? ?? ??? ??????? ????? ???? ????? ????????[169] ??? ???? ????? ???? ??? ????? ?????? ???? ?? ?????? ????? ???????? ???? ???? ?? ???????? ??????? ?????????[169] ????? ????? ???????.[126]

????? ??????

[???]
??? ?????? ?????

????? ????? ?????? ???????? ?? ????? 8% ?? ???????? ??? ????? ????? ??????? ?? ?????? ?????? ??? ???? ???????[170] ???? ???? ?????? ??????? ?? ??? ????????? ?? ??? ????? ?? ?????? ????? ?????? ?? ????? ?????? ???????? ???????? ??? ?????????? ?????????? ?? ??????? ??????? ????????? ?????? ????? ?????? ?????? ??????? ???? ?? ????? ???????.[de 37]

??? ?????? ??????

???? ?????? ????? ????? ?? ??????? ??? ?????? ???????? ?? ???? ?? ????????? ???????? ????? ????????[171] ???? ????? ??? ??????? ?????? ??? ??????? ???????? [?????? 166] ??? ???????? [?????? 167].[172] ???? ???? ???????? ?????? ??????? ??????? ????? ?? ????? ?????? ????? ???? ???? ????? ??????? ???? ??????? ?????? ?????????.[173]

???? ?????? ?? ???? ?????? ?????? ?????? ?? ????? ?? ???? ?????? ???????? ?? ????? ?????? ?? ?????? ??????. ??? ???? ?????? ??? ???????? ???? ?????? ??? ????? ????? ?? ???? ????? ??? ???? ????? ??????? ??? ??????? ??????.[174] ???? ?? ?????? ??????? ?? ??????? ????????? ???? ?????? ?????? ???? ????? ??????? ?? ????? ?????? ?????? ?? ????????.[175] ?? ???? ?????? ?????? ??? ??? ?????? ?? ??????? ??????? ??????? ??? ???????? ?????? ????????? ???? ????? ?? ?????? ??????? ?????? ?????? ??? ??????.[176] ????? ????? ????? ???????? ??? ????? ?????? ?????? ??? ???? ????? ????? ???????? ?? ???????? ???????.[177]

???????????

[???]
????? ??????? [?????? 168] ???? ??? ????? ?? ?????? ?????? ????? ???? ????? ????? ??? ?? ??? ???? 1779-1780.

???? ???? ?????? ???? ???????? ????????? ?? ??????? ?????? ???????? ??? ????? 90% ?? ????? ???????? ???????? ???? ?? ?????? ???????? ??? ???? ????? ?? ????????? ???????? ????????? ?????? ??? ????????? ???????? ?????? ????? ???? ?????? ?????? ??????.[178]

????? ???????

??? ????????? ?????? ??????? ?????? ?? ??? ??? ????? ?? ???????? ???? ??? ???? ????? ??????? (?? ?????) ?? ??? ???? ???? ??? (???? ????). ???? ????? ?? ???? ??????? ?????? ?? ?????? ???????? ??? ????? ??????? ??????? ???? ???? ?? ???? ?????? ??????? ????????? ?? ???????? ??????? ???????? ??? ????? ????? ?????? ????????? ??????? ?????? ????? ?? ????? ??????? ???????? ???????? ???????? ??? ????? ?? ?????? ????? ??? ?????? ???????????? ??????? ??? ???? ??????? ???? ?????? ?????? ?????? ?? ?????? ?? ????????? ???????.[de 38]

?????? ???????? ?????? ???????

????? ?????? ???????? ?????? ?? ???? ???????? ???? ?? ???? ?????? ??????? ??????? ?????? ???????? ???????? ??????????? ?????? ?????? ???????? ??? ???? ?????? ?????????? ??????? ?? ??????? ?????? ???????.[de 20]

???????????????

????? ?????? ??? ???? ???????? ??????? ??? ???????? ??? ??????????? ????????? ???? ????? ?????? ????? ?? ???? ????????? ?????????? ?????????? ????????? ??????? [?????? 169] ???????????? [?????? 170] ?????????? ???????????[de 31] ????? ?? ????? ???? ???????.[de 39][de 40]

?????? ??????

?????? ??????? ?????? ?? ???? ???????? ???? ??? ????? ????-??? ?? ????? ????-?????.[de 41] ??? ???????? ????? ?????? ?? ??? ???? ?? ??? ????? ?????? ?????? ?????? ????? ???? ??????? ??? ??????.[179] ???? ????????? ???????? ??? ?????? ????? ????? ?? ????? ?????? ???????? ??????? ??? ???? ????? ????????? ?? ???? ?????? ???????[180] ????? ?? ????? ?????????? ??????? ??????? [?????? 171]?[181][182] ?????? ???????[183] ???????? ??? ????? ?????? ?????????? ?????? ?? ?????.[184] ???????? ??????? ?????? ????????? ????? ????? ?? ???? ????? ?????? ??????? ????? ?????? ??? ???? ??????? ????????? ???????????.[143] ??? ???????? ??????? ?????? ?????? ??? ?????? ?? ?????? ??? ????? ??????? ??? ???? ?????? ?? ??? ??????.[de 42]

?? ?????? ???????? ??????

[???]

?? ???????

[???]

???? ???? ???? ?? ??? ????? ?? ?????? ??????? ????? ???? ?? ?????? ?? ???? ?????? ??? ???? ????? ?????? ?? ??????? ??? ?????: ??????? ??????????? ????????? ??????????????? ????????????? ???????? ?????????? ????????????? ????????? ???????? ??????????? ????????????? ?????????? ????? ?????? ??????? ??????????? ????????? ???????????? ??????? ???? ?????????? ?????????? ??????????? ????? ??????? ??????? ??????? ???? [??????:25]

?? ?????

[???]
????? ???? ???? ??? ???? ????? ???????? ??????? ?????? ???? ?????? ????????? ???????? ?????? ?????? ?????? [?????? 172].
????? ???????

???? ??? ????? ?? ???? ???? ????? ????: ???????: ??? ?????? ??????? ????? ????? ?????? ??? ?????? ?????? ?????? ????????? ??? ??????.[ar 4]

?????? ????????

???? ??????? ????? ????????? ?????? Fe ?? ?????? ????????? ferrum. ???? ??? ???? Iron ?? ????? ??????????? ??? ??? ????? ?????? ???????? ????? Eisen ?????????? ??? ???? ??? ????? *isarn ?? ????? ????????? ?????????[185] ????? ?? ???? ???????? ?? ????? ??????? [?????? 173]? ?? ??? ??? ??? ????? ?? ????? ????????? [?????? 174] ??? ?????.[de 43]

????? ???????

[???]

????? ????? ?? ?????? ???? ?????? ??????? ??? ?????? ???? ?????? ???? ?? ????? ?? ?????? ?????? ?????????. ??????? ???????? ??????? [?????? 175] ???? ?? ????? ??????? ??????? ?????? ?? ???? ??????? ?????? ????? ??? ?????? ??? ????? ?????? ????????? ???????? ??????? ??? ?????? ????????? ?????? ???????.[186]

???? ????? ?????? ?????? ?? ????? ?????? ???????? ??????? ??? ??? ?????? ????????? ???? 1813? ?? ??? ?????? ?????? ?????? ??? ?????? [?????? 176] ???? ???? ?????? ?? ?????? ??????? ??????? ???????? ?????? ????????? ???????? ???????? ???? ?????? ??? ??? ????? ????????? ??? ??????? ?????? ??????? ?? ??? ???? ?????? ????? ???????.[de 44]

???? ?????

[???]

???????

[???]
  1. ^ ???? ??????? ?? ??? ??????? ???????
  2. ^ ???? ????? ?????? ?????
  3. ^ Meteoritic iron
  4. ^ Cape York meteorite
  5. ^ Cast iron
  6. ^ Anitta
  7. ^ Bloomery
  8. ^ Termit Massif
  9. ^ Taruga
  10. ^ Atharvaveda
  11. ^ Wootz steel
  12. ^ Cupola furnace
  13. ^ finery forge
  14. ^ Abraham Darby I
  15. ^ Henry Cort
  16. ^ puddling
  17. ^ Henry Bessemer
  18. ^ Bessemer process
  19. ^ Widmanst?tten pattern
  20. ^ runaway fusion
  21. ^ Type Ia supernova
  22. ^ Taenite
  23. ^ kamacite
  24. ^ Bog iron
  25. ^ Telluric iron
  26. ^ Disko Island
  27. ^ Roussillon
  28. ^ periclase
  29. ^ wüstite
  30. ^ Ferropericlase
  31. ^ magnesiowüstite
  32. ^ Silicate perovskite
  33. ^ ringwoodite
  34. ^ hematite
  35. ^ magnetite
  36. ^ siderite
  37. ^ Limonite
  38. ^ Goethite
  39. ^ pyrrhotite
  40. ^ pentlandite
  41. ^ pyrite
  42. ^ ochre
  43. ^ Buntsandstein
  44. ^ International Resource Panel
  45. ^ El Mutún
  46. ^ Kiruna mine
  47. ^ Sintering
  48. ^ Pelletizing
  49. ^ United States Geological Survey (USGS)
  50. ^ World Steel Association
  51. ^ pig iron ????? ????? ????? ?????? ?????? ?? ?????? ?????
  52. ^ Blast furnace ????? ???? ????? ????? ??????
  53. ^ Blast furnace gas (BFG)
  54. ^ slag
  55. ^ cast iron
  56. ^ foundries
  57. ^ cold working
  58. ^ hot rolling
  59. ^ forging
  60. ^ machining
  61. ^ Annealing
  62. ^ sponge iron
  63. ^ open hearth furnace
  64. ^ Thomas Process
  65. ^ basic oxygen furnace
  66. ^ Sinter plant
  67. ^ Corex Process
  68. ^ Type II supernova
  69. ^ enthalpy of atomization
  70. ^ body-centered cubic (bcc) crystal structure
  71. ^ face-centered cubic (fcc) crystal structure
  72. ^ Austenite
  73. ^ Ferrite
  74. ^ Curie point
  75. ^ Paramagnetism
  76. ^ Ferromagnetism
  77. ^ spin
  78. ^ Magnetic domain
  79. ^ Tensile strength
  80. ^ Castability
  81. ^ white cast iron
  82. ^ cementite
  83. ^ pearlite
  84. ^ martensite
  85. ^ gray cast iron
  86. ^ Stress concentration
  87. ^ ductile cast iron
  88. ^ Carbon steel
  89. ^ Hardening
  90. ^ Rolling
  91. ^ Alloy steel
  92. ^ High-strength low-alloy steel (HSLA)
  93. ^ Pourbaix diagram
  94. ^ Potassium ferrate(VI)
  95. ^ mixed valence compound
  96. ^ Maghemite
  97. ^ Bluing
  98. ^ Lepidocrocite
  99. ^ Hydratation
  100. ^ Pyrite
  101. ^ hexachloroferrate(III)
  102. ^ tetrakis(methylammonium) hexachloroferrate(III) chloride
  103. ^ high-spin
  104. ^ trans
  105. ^ chlorohydridobis(bis-1,2-(diphenylphosphino)ethane)iron(II)
  106. ^ ferrioxalate
  107. ^ Axial chirality
  108. ^ Sandwich compound
  109. ^ Half sandwich compound
  110. ^ Metallocene
  111. ^ carbonyl iron
  112. ^ triiron dodecacarbonyl
  113. ^ Collman's reagent
  114. ^ Kn?lker complex
  115. ^ rhodanide
  116. ^ galvanization
  117. ^ Passivation
  118. ^ Oct-1-en-3-one
  119. ^ Lipid peroxidation
  120. ^ ferritin
  121. ^ hemoglobin
  122. ^ myoglobin
  123. ^ cytochrome P450
  124. ^ Metalloproteins
  125. ^ Rubredoxin
  126. ^ Catalase
  127. ^ Lipoxygenase
  128. ^ Iron-responsive element-binding protein
  129. ^ ferredoxins
  130. ^ Siderophore
  131. ^ transferrin
  132. ^ distorted octahedron
  133. ^ chelating
  134. ^ ferritin
  135. ^ deoxyhemoglobin
  136. ^ high-spin configuration
  137. ^ low-spin configuration
  138. ^ carboxyhemoglobin
  139. ^ Ferrichrome
  140. ^ Streptomyces
  141. ^ Annelid
  142. ^ Hemerythrin
  143. ^ National Academy of Medicine
  144. ^ Institute of Medicine (IoM)
  145. ^ Estimated Average Requirements (EARs)
  146. ^ Recommended Dietary Allowance (RDA)
  147. ^ Tolerable upper intake levels (ULs)
  148. ^ European Food Safety Authority (EFSA)
  149. ^ Daily Value (%DV)
  150. ^ Iron deficiency
  151. ^ latent iron deficiency
  152. ^ iron-deficiency anemia
  153. ^ hepcidin
  154. ^ iron overload disorder
  155. ^ Hereditary haemochromatosis
  156. ^ free iron
  157. ^ Iron poisoning
  158. ^ Siderosis
  159. ^ metabolic acidosis
  160. ^ coagulopathy
  161. ^ Acute respiratory distress syndrome
  162. ^ deferoxamine
  163. ^ Salmonellosis
  164. ^ Yersiniosis
  165. ^ Attention deficit hyperactivity disorder (ADHD)
  166. ^ Phytoplankton
  167. ^ diatoms
  168. ^ The Iron Bridge
  169. ^ Choke
  170. ^ Relay
  171. ^ fine chemicals
  172. ^ Gold gab ich für Eisen
  173. ^ Celtic language
  174. ^ Illyrian language
  175. ^ Hesiod
  176. ^ Friedrich Wilhelm III.

???????

[???]

???? ???????

[???]
????????
  1. ^ ???? ????? ???????? (2018). ??? ??????. ????? ??????? ???????. ????? ?? ????? ?? 2025-08-14.
  2. ^ ? . ???? ?? ??? ???? ??????, ???? ??? ????? ??????, ? . ???? ???? ??? ?????? ??? (2005). ?????? ??????? ??????????. ????? ???????? - ??????. ?. 374. ISBN:9789960407364. ????? ?? ????? ?? 2025-08-14.{{??????? ?????}}: ????? ?????????: ????? ??????: ????? ???????? (link)
  3. ^ ?????? ???? (2011). ???????? ?????????? ??????? ??? ????? ???????? ??????? ?????. Dar Annashr For Universit. ?. 53. ISBN:9796500031194. ????? ?? ????? ?? 2025-08-14.
  4. ^ ??? ????? (1994)? ???? ????? (?. 3)? ?????: ??? ????? ?. 3? ?. 141? OCLC:4770578388? QID:Q114878607
??????????
  1. ^ ? ? ? ? ? Florian Neukirchen (2016). Von der Kupfersteinzeit zu den Seltenen Erden – Eine kurze Geschichte der Metalle (??????????). Springer-Verlag. p. 65. ISBN:978-3-662-49347-2.
  2. ^ ? ? ? ? ? ? Otto Johannsen (1953). "Geschichte des Eisens". Auflage (??????????). 3: 6–45.
  3. ^ Otto Johannsen (1975). "Eisen". In Eberhard Otto (ed.). Lexikon der ?gyptologie (??????????). Wiesbaden: Harrassowitz. Vol. 1. pp. 1209–1210.
  4. ^ Ure, Andrew (1843). Technisches w?rterbuch oder Handbuch der Gewerbskunde ... : Bearb. nach Dr. Andrew Ure's Dictionary of arts, manufactures and mines (??????????). G. Haase. p. 492.
  5. ^ Pigott, Vincent C. (1999). The Archaeometallurgy of the Asian Old World (??????????). Philadelphia: University of Pennsylvania Museum of Archaeology and Anthropology. p. 191. ISBN:0-924171-34-0.
  6. ^ Riederer, Josef; Wartke, Ralf-B. (2006). "Eisen". Der Neue Pauly (??????????). DOI:10.1163/1574-9347_bnp_e327700. Archived from the original on 2025-08-14.
  7. ^ Sophus Müller (2019). Otto Luitpold Jiriczek (ed.). Eisenzeit (??????????) (1 ed.). Walter de Gruyter GmbH & Co KG. p. 9. ISBN:978-3-11-144101-6.
  8. ^ Erik Myrstener; William Lidberg; Ulf Segerstr?m; Harald Biester; David Damell; Richard Bindler (2016). "Was Moshyttan the earliest iron blast furnace in Sweden? The sediment record as an archeological toolbox". Journal of Archaeological Science: Reports (???????????). 5: 35–44. DOI:10.1016/j.jasrep.2015.10.040. Archived from the original on 2025-08-14.
  9. ^ Hans Berns; Werner Theisen (2008). "Eisenwerkstoffe – Stahl und Gusseisen" (???????????). Springer-Verlag: 396. DOI:10.1007/978-3-540-79957-3. ISBN:978-3-540-79955-9. Archived from the original on 2025-08-14. {{??????? ?????? ?????}}: ????????? ?????? ????? ???? |????? ?????= (help)
  10. ^ Klaus Urban (2015). Materialwissenschaft und Werkstofftechnik Ein Ritt auf der Rasierklinge (???????????). Springer-Verlag. p. 28. DOI:10.1007/978-3-662-46237-9. ISBN:978-3-662-46237-9. Archived from the original on 2025-08-14.
  11. ^ Claude Allègre; Gérard Manhès; éric Lewin (2001). "Chemical composition of the Earth and the volatility control on planetary genetics". Earth and Planetary Science Letters (???????????). 185 (1–2): 49–69. DOI:10.1016/S0012-821X(00)00359-9. Archived from the original on 2025-08-14.
  12. ^ Harry H. Binder (1999). Lexikon der chemischen Elemente (??????????). Stuttgart: S. Hirzel Verlag. ISBN:3-7776-0736-3.
  13. ^ Mathias Scholz (2004). Die Physik der Sterne (??????????). Heidelberg: Springer Spektrum Berlin. DOI:10.1007/978-3-662-57801-8. ISBN:978-3-662-57800-1. Archived from the original on 2025-08-14.
  14. ^ John Grotzinger; Thomas Jordan (2017). Press/Siever Allgemeine Geologie (??????????). Translated by Volker Schweizer (7 ed.). Heidelberg: Springer Spektrum Berlin. p. 11. DOI:10.1007/978-3-662-48342-8. ISBN:978-3-662-48341-1. Archived from the original on 2025-08-14.
  15. ^ Slobodan Jankovic (1967). Wirtschaftsgeologie der Erze (??????????) (1 ed.). Springer Vienna. p. 96. DOI:10.1007/978-3-7091-5100-6. ISBN:978-3-7091-5100-6. Archived from the original on 2025-08-14.
  16. ^ ? ? Martin Bertau; Armin Müller; Peter Fr?hlich; Michael Katzberg (2013). Industrielle Anorganische Chemie (??????????). John Wiley & Sons. p. 696, 252. ISBN:978-3-527-33019-5. Archived from the original on 2025-08-14.
  17. ^ "Banded Iron Formation". spektrum.de (??????????). 2019. Archived from the original on 2025-08-14. Retrieved 2025-08-14.
  18. ^ H. Berns, L. Scheer (2013). Was ist Stahl – Eine Stahlkunde für jedermann (??????????). Springer-Verlag. p. 100. ISBN:978-3-642-61846-8.
  19. ^ ? ? Heinz Max Hiersig (2013). VDI-Lexikon Maschinenbau (??????????). Springer-Verlag. p. 520. DOI:10.1007/978-3-642-57850-2. ISBN:978-3-642-57850-2. Archived from the original on 2025-08-14.
  20. ^ ? ? Wolfgang Bleck, Elvira Moeller (2017). Handbuch Stahl Auswahl, Verarbeitung, Anwendung (??????????). Carl Hanser Verlag GmbH Co KG. p. 78,386. ISBN:978-3-446-44962-6.
  21. ^ ? ? ? ? ? ? ? ? ? ? ?? ?? ?? ?? ?? Holleman, Arnold F.; Wiberg, Egon; Wiberg, Nils (1985). "Iron". Lehrbuch der Anorganischen Chemie (??????????). Walter de Gruyter (published 1901). pp. 1125–46. ISBN:3-11-007511-3.
  22. ^ Ludwig von Bogdandy (2013). "Die Reduktion der Eisenerze Wissenschaftliche Grundlagen und technische Durchführung" (??????????). Heidelberg: Springer Berlin,. p. 33. DOI:10.1007/978-3-642-92935-9. ISBN:978-3-642-92935-9. Archived from the original on 2025-08-14.{{??????? ???}}: ????? ?????????: ?????? ????? ????? (link)
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